Kutrovskaya Stella, Samyshkin Vlad, Lelekova Anastasia, Povolotskiy Alexey, Osipov Anton, Arakelian Sergey, Kavokin Alexey Vitalievich, Kucherik Alexey
School of Science, Westlake University, 18 Shilongshan Road, Hangzhou 310024, China.
Institute of Natural Sciences, Westlake Institute for Advanced Study, 18 Shilongshan Road, Hangzhou 310024, China.
Nanomaterials (Basel). 2021 Mar 17;11(3):763. doi: 10.3390/nano11030763.
The formation of macroscale carbon structures characterised by an sp-sp2-hybridization is realised by self-assembly in colloidal solutions under an effect of laser irradiation and electromagnetic fields. The sponge-like morphology, sculptured with gold nanoparticles (NPs) was revealed by Scanning Electron Microscopy (SEM) imaging. Full structural and defect characterization of the self-assembled sponges was provided using the micro-Raman spectroscopic technique. The synthesized clusters manifest themselves in the presence of a strong spectral band in the visible range of the photoluminescence spectra that is quite unusual for ordered sp2-carbon systems.
通过在激光辐照和电磁场作用下在胶体溶液中进行自组装，实现了以sp-sp2杂化特征的宏观碳结构的形成。用扫描电子显微镜（SEM）成像揭示了用金纳米颗粒（NPs）雕刻的海绵状形态。使用显微拉曼光谱技术对自组装海绵进行了完整的结构和缺陷表征。合成的团簇在光致发光光谱的可见范围内存在强光谱带，这对于有序的sp2碳系统来说是非常不寻常的。
