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纳秒脉冲电场下氮化硼纳米片的介电泳运动模拟

Simulation of BNNSs Dielectrophoretic Motion under a Nanosecond Pulsed Electric Field.

作者信息

Mi Yan, Ge Xin, Dai Jinyan, Chen Yong, Zhu Yakui

机构信息

State Key Laboratory of Power Transmission Equipment & System Security and New Technology, School of Electrical Engineering, Chongqing University, Chongqing 400044, China.

出版信息

Nanomaterials (Basel). 2021 Mar 9;11(3):682. doi: 10.3390/nano11030682.

Abstract

Using a nanosecond pulsed electric field to induce orientation and arrangement of insulating flake particles is a novel efficient strategy, but the specific mechanism remains unclear. In this study, the dielectrophoretic motion of boron nitride nanosheets (BNNSs) in ultrapure water under a nanosecond pulsed electric field is simulated for the first time. First, the simulation theory is proposed. When the relaxation polarization time of the dielectric is much shorter than the pulse voltage width, the pulse voltage high level can be considered a short-term DC voltage. On this basis, the Arbitrary Lagrangian-Euler (ALE) method is used in the model, considering the mutual ultrapure water-BNNS particles-nanosecond pulsed electric field dielectrophoretic interaction, to study the influence of different BNNSs self-angle α and relative angle β on local orientation and global arrangement. The particles are moved by the dielectrophoretic force during the pulse voltage high level and move with the ultrapure water flow at the zero level, without their movement direction changing during this period, so the orientation angle and distance changes show step-like and wave-like curves, respectively. The model explains the basic mechanism of dielectrophoretic motion of BNNSs under a pulsed electric field and summarizes the motion law of BNNSs, providing a reference for subsequent research.

摘要

利用纳秒脉冲电场诱导绝缘片状颗粒的取向和排列是一种新型高效策略,但具体机制尚不清楚。本研究首次模拟了纳秒脉冲电场作用下氮化硼纳米片(BNNSs)在超纯水中的介电泳运动。首先,提出了模拟理论。当电介质的弛豫极化时间远短于脉冲电压宽度时,脉冲电压高电平可视为短期直流电压。在此基础上,模型采用任意拉格朗日-欧拉(ALE)方法,考虑超纯水-BNNS颗粒-纳秒脉冲电场介电泳相互作用,研究不同BNNSs自转角α和相对角β对局部取向和全局排列的影响。颗粒在脉冲电压高电平时受介电泳力作用移动,在零电平时随超纯水流动移动,在此期间其运动方向不变,因此取向角和距离变化分别呈现阶梯状和波浪状曲线。该模型解释了BNNSs在脉冲电场下介电泳运动的基本机制,总结了BNNSs的运动规律,为后续研究提供了参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4445/8000861/50b19c977af2/nanomaterials-11-00682-g001.jpg

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