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基于化学发泡剂浓度的天然橡胶泡沫的形态与弹性之间的关系

The Relationship between the Morphology and Elasticity of Natural Rubber Foam Based on the Concentration of the Chemical Blowing Agent.

作者信息

Suethao Supitta, Phongphanphanee Saree, Wong-Ekkabut Jirasak, Smitthipong Wirasak

机构信息

Specialized Center of Rubber and Polymer Materials in Agriculture and Industry (RPM), Department of Materials Science, Faculty of Science, Kasetsart University, Bangkok 10900, Thailand.

Department of Physics, Faculty of Science, Kasetsart University, Bangkok 10900, Thailand.

出版信息

Polymers (Basel). 2021 Mar 30;13(7):1091. doi: 10.3390/polym13071091.

Abstract

Concentrated natural latex was used to produce a rubber foam that is porous, elastic and well ventilated. The mechanical properties can be either soft or firm, depending on the formulation of the latex used. Briefly, concentrated natural latex was mixed with chemical agents to make the rubber foam on a laboratory scale using the Dunlop process. In this work, we changed the concentration of the chemical blowing agent in the latex. The morphological properties of the rubber foam were characterised using scanning electron microscopy, and the mechanical properties, or elasticity, were studied using compression experiments and the Mooney-Rivlin calculation. The results show that the concentration of the chemical blowing agent affects the morphological properties of the rubber foam but not the mechanical properties, indicating the heterogeneous structure of the rubber foam. The thermodynamic parameters (∆ and ∆) and the internal energy force per compression force (/) of the rubber foam with various amounts of chemical blowing agent were also investigated. This study could be applied in the foam industry, particularly for pillow, mattress and insulation materials, as the present work shows the possible novel control of the morphological structure of the rubber foam without changing its mechanical properties. The difference in cell sizes could affect the airflow in rubber foam.

摘要

浓缩天然乳胶被用于生产一种多孔、有弹性且通风良好的橡胶泡沫。其机械性能可以是柔软的也可以是坚硬的,这取决于所使用乳胶的配方。简要来说,在实验室规模下,使用邓禄普工艺将浓缩天然乳胶与化学试剂混合以制备橡胶泡沫。在这项工作中,我们改变了乳胶中化学发泡剂的浓度。使用扫描电子显微镜对橡胶泡沫的形态特性进行了表征,并通过压缩实验和穆尼 - 里夫林计算研究了其机械性能或弹性。结果表明,化学发泡剂的浓度会影响橡胶泡沫的形态特性,但不会影响其机械性能,这表明橡胶泡沫具有非均匀结构。还研究了含有不同量化学发泡剂的橡胶泡沫的热力学参数(∆ 和 ∆)以及每次压缩力下的内能(/)。这项研究可应用于泡沫行业,特别是用于枕头、床垫和绝缘材料,因为目前的工作表明在不改变橡胶泡沫机械性能的情况下,有可能对其形态结构进行新颖的控制。泡孔尺寸的差异可能会影响橡胶泡沫中的气流。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3942/8036522/bd4e47e791cb/polymers-13-01091-g001.jpg

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