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用含镍双功能催化剂进行甘油氢解制备丙醇。

Preparation of Propanols by Glycerol Hydrogenolysis over Bifunctional Nickel-Containing Catalysts.

机构信息

N.D. Zelinsky Institute of Organic Chemistry, Leninsky Prospect, 47, 119991 Moscow, Russia.

Chemistry Department, Lomonosov Moscow State University, Leninskie Gory, 1, bldg. 3, 119991 Moscow, Russia.

出版信息

Molecules. 2021 Mar 12;26(6):1565. doi: 10.3390/molecules26061565.

DOI:10.3390/molecules26061565
PMID:33809129
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8001030/
Abstract

The paper presents the results obtained in studying glycerol hydrogenolysis into 1-propanol and 2-propanol over bifunctional Ni/WO-TiO and Ni/WO-ZrO catalysts in the flow system. Due to the optimal combination of acidic and hydrogenation properties of the heterogeneous catalysts, they exhibit higher performance in glycerol conversion into C alcohols, although the process is carried out in rather mild conditions. At the reaction temperature of 250 °C and hydrogen pressure of 3 MPa, the total yield of 1-propanol and 2-propanol reaches 95%, and the glycerol conversion is close to 100%.

摘要

本文介绍了在流动系统中使用双功能 Ni/WO-TiO 和 Ni/WO-ZrO 催化剂研究甘油氢解为 1-丙醇和 2-丙醇的结果。由于多相催化剂的酸性和加氢性能的最佳组合，它们在甘油转化为 C 醇的过程中表现出更高的性能，尽管反应条件相当温和。在反应温度为 250°C 和氢气压力为 3 MPa 的条件下，1-丙醇和 2-丙醇的总收率达到 95%，而甘油转化率接近 100%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/aa513ae39074/molecules-26-01565-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/4cad80a1d1d9/molecules-26-01565-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/2dd4229e3d4e/molecules-26-01565-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/9e3d16335136/molecules-26-01565-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/131687879b12/molecules-26-01565-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/9b8fa141522a/molecules-26-01565-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/ba5fbf3d8e69/molecules-26-01565-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/aa513ae39074/molecules-26-01565-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/4cad80a1d1d9/molecules-26-01565-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/2dd4229e3d4e/molecules-26-01565-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/9e3d16335136/molecules-26-01565-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/131687879b12/molecules-26-01565-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/9b8fa141522a/molecules-26-01565-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/ba5fbf3d8e69/molecules-26-01565-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/20ce/8001030/aa513ae39074/molecules-26-01565-g007.jpg

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本文引用的文献

1
Structures and reaction mechanisms of glycerol dehydration over H-ZSM-5 zeolite: a density functional theory study.甘油在 H-ZSM-5 沸石上脱水的结构和反应机理：密度泛函理论研究。
Phys Chem Chem Phys. 2011 Apr 14;13(14):6462-70. doi: 10.1039/c0cp01720e. Epub 2011 Mar 3.
2
From glycerol to value-added products.从甘油到增值产品。
Angew Chem Int Ed Engl. 2007;46(24):4434-40. doi: 10.1002/anie.200604694.