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从一个煤气工业城市(中国西北部)综合筛查全环境中的铅和其他有毒金属:基于特定源的综合风险和 0-6 岁儿童特定地点的血铅水平。

Comprehensive screen the lead and other toxic metals in total environment from a coal-gas industrial city (NW, China): Based on integrated source-specific risks and site-specific blood lead levels of 0-6 aged children.

机构信息

Department of Environmental Science, School of Geograph and Tourim, Shaanxi Normal University, Xi'an, Shaanxi, 710062, PR China; International Joint Research Centre of Shaanxi Province for Pollutant Exposure and Eco-environmental Health, Xi'an, Shaanxi, 710062, PR China.

Department of Environmental Science, School of Geograph and Tourim, Shaanxi Normal University, Xi'an, Shaanxi, 710062, PR China; International Joint Research Centre of Shaanxi Province for Pollutant Exposure and Eco-environmental Health, Xi'an, Shaanxi, 710062, PR China.

出版信息

Chemosphere. 2021 Sep;278:130416. doi: 10.1016/j.chemosphere.2021.130416. Epub 2021 Mar 31.

Abstract

A new integrated source-specific risk model and site-specific blood lead levels (BLLs) of 0-6 children were introduced to comprehensive understand the status of the toxic metals in soil-dust-plant total environment from a Coal-Gas industrial city, NW China. 144 samples were collected and ten toxic metals (As, Ba, Co, Cr, Cu, Mn, Ni, Sr, Pb, and Zn) were screened by XRF and ICP-MS. It was found that the occurrences of toxic metals deferred in the different medium, such as Co, Cu, Pb, and Zn observed the trend of accumulating in soil and plant compared to clustered distributions of Cr, Mn and Ni preferred to accumulate in dust. However, few bioaccumulations observed in Ulmus pumila L. Toxic metals distributions in majority of sites influenced by coal combustion mixed sources and industrial activities posed the high integrated ecological risks and caused significant non-carcinogenic and carcinogenic integrated risks for local 0-6 children identified by new integrated source-specific risk model, especially observed in the priority contaminants Co and Pb. The site-specific BLLs confirmed that younger children fewer than 4 lived in the north region were more vulnerable to priority Pb pollution as their BLLs above 50 μg/L, almost up to 80 μg/L. Although proportions of source-specific risks to toxic metals changed in soil and dust, the critical sources from coal combustions and industrial activities posed the most important contribution to the local risks. Therefore, effective strategies targeting at critical sources on coal industries should be conducted to reduce risks, and mostly emphasize on the north hotspot areas.

摘要

为了全面了解中国西北某煤气化工业城市土壤-灰尘-植物总环境中有毒金属的污染状况,引入了一种新的基于污染源的综合风险模型和 0-6 岁儿童的特定地点血铅水平(BLL)。采集了 144 个样本,并用 XRF 和 ICP-MS 筛选了十种有毒金属(As、Ba、Co、Cr、Cu、Mn、Ni、Sr、Pb 和 Zn)。结果发现,有毒金属在不同介质中的存在方式不同,如 Co、Cu、Pb 和 Zn 在土壤和植物中的积累趋势较为明显,而 Cr、Mn 和 Ni 则更倾向于在灰尘中聚集。然而,在榆叶梅中观察到的生物积累现象较少。大多数采样点的有毒金属分布受到燃煤混合源和工业活动的影响,新的综合污染源特定风险模型评估认为该地区 0-6 岁儿童面临着较高的综合生态风险,并存在显著的非致癌和致癌综合风险,特别是在优先污染物 Co 和 Pb 方面。特定地点的 BLL 证实,居住在北部地区、年龄小于 4 岁的儿童更容易受到优先 Pb 污染的影响,因为他们的 BLL 超过 50μg/L,几乎达到 80μg/L。尽管土壤和灰尘中有毒金属的污染源特定风险比例发生了变化,但燃煤和工业活动的关键污染源对当地风险的贡献最大。因此,应针对煤炭产业的关键污染源采取有效策略来降低风险,特别是在北部热点地区。

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