Rodriguez Jessica, Conley Matthew P
Department of Chemistry, University of California-Riverside (UCR), Riverside, California 92521, United States.
Inorg Chem. 2021 May 17;60(10):6946-6949. doi: 10.1021/acs.inorgchem.1c00454. Epub 2021 Apr 12.
PAr containing -OMe, -Me, or -Et substituents reacts with Brønsted sites on sulfated zirconium oxide () to form [HPAr][]. The phosphonium sites on this material react with bis(cyclooctadiene)nickel [Ni(cod)] to form [Ni(PAr)(codH)][] that are active in ethylene polymerization reactions. Selective poisoning studies with pyridine show that ∼90% of the Ni(PAr)(codH) sites in this material are active in polymerization reactions.
含有-OMe、-Me或-Et取代基的膦（PAr）与硫酸化氧化锆（）上的布朗斯特位点反应形成[HPAr][ ]。该材料上的鏻位点与双（环辛二烯）镍[Ni（cod）]反应形成[Ni（PAr）（codH）][ ]，它们在乙烯聚合反应中具有活性。用吡啶进行的选择性中毒研究表明，该材料中约90%的Ni（PAr）（codH）位点在聚合反应中具有活性。
