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A Tellurium-Substituted Heteropolyniobate with Unique π-π Stacking and Ionic Conduction Property.

作者信息

Wu Ping-Xin, Lai Rong-Da, Ge Rui, Sun Cai, Wang Guo-Qiang, Li Xin-Xiong, Zheng Shou-Tian

机构信息

State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.

College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China.

出版信息

Inorg Chem. 2021 May 3;60(9):6162-6166. doi: 10.1021/acs.inorgchem.1c00754. Epub 2021 Apr 19.

DOI:10.1021/acs.inorgchem.1c00754
PMID:33871999
Abstract

A tetratellurium-substituted heteropolyoxoniobate with the formula KH[Cu(phen)(HO)][Cu(phen)][(LiNbTeO)]·34HO (; phen = 1,10-phenanthroline) was hydrothermally prepared and structurally characterized. The compound represents the first hexavalent tellurium-substituted Keggin-type polyoxometalate (POM) so far. What is more, the POM cluster in can elaborately self-assemble into a stable supramolecular framework with an ion conduction property through unique intermolecular π-π stacking.

摘要

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