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用金刚石线锯切割硅废料制备 Al-Si 合金。

Preparation of Al-Si alloys with silicon cutting waste from diamond wire sawing process.

机构信息

School of Metallurgy, Northeastern University, Shenyang, 110819, PR China.

Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang, 110819, China.

出版信息

J Environ Manage. 2021 Jul 15;290:112548. doi: 10.1016/j.jenvman.2021.112548. Epub 2021 Apr 17.

Abstract

Large amounts of silicon cutting waste (SCW) are generated during Si wafers producing process. In this paper, SCW was mixed with Al powder to prepare Al-Si alloys by a one-step smelting process in corundum crucibles. The influences of smelting temperature (1000 °C, 1200 °C and 1500 °C) on the products of each zone (surface layer zone, loose granular zone and blocky products zone) were investigated. Al-Si alloys in the form of granular and blocky were prepared and the blocky Al-Si alloys mainly concentrated in the blocky products zone. The increase of smelting temperature can promote the aggregation of Al-Si alloy particles. The yields of Al-Si alloy blocks obtained at 1000 °C, 1200 °C and 1500 °C were 0%, 58% and 69%, respectively. The Si contents of Al-Si alloy blocks at 1200 °C and 1500 °C were 15.8 wt% and 17.1 wt% respectively. After compacting the raw materials, the yields of the blocky Al-Si alloys obtained at 1000 °C, 1200 °C and 1500 °C were increased to 65%, 72% and 79% and the corresponding Si contents of the blocky Al-Si alloys were increased to 16.0 wt%, 16.5 wt% and 17.3 wt% respectively. The reaction mechanism of the alloying process was also investigated.

摘要

大量的硅切割废料(SCW)在硅片生产过程中产生。本文采用一步熔炼法,在刚玉坩埚中,将 SCW 与 Al 粉混合制备 Al-Si 合金。研究了熔炼温度(1000°C、1200°C 和 1500°C)对各区域(表面层区、疏松颗粒区和块状产品区)产物的影响。以颗粒状和块状形式制备了 Al-Si 合金,块状 Al-Si 合金主要集中在块状产品区。熔炼温度的升高可以促进 Al-Si 合金颗粒的聚集。在 1000°C、1200°C 和 1500°C 下获得的块状 Al-Si 合金的产率分别为 0%、58%和 69%。在 1200°C 和 1500°C 下获得的块状 Al-Si 合金中 Si 的含量分别为 15.8wt%和 17.1wt%。压实原料后,在 1000°C、1200°C 和 1500°C 下获得的块状 Al-Si 合金的产率分别提高到 65%、72%和 79%,相应的块状 Al-Si 合金中 Si 的含量分别提高到 16.0wt%、16.5wt%和 17.3wt%。还研究了合金化过程的反应机理。

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