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电-Fenton 法再生颗粒状活性炭:有机污染物的降解与碳表面的关系。

The electro-Fenton regeneration of Granular Activated Carbons: Degradation of organic contaminants and the relationship to the carbon surface.

机构信息

Department of Chemical Engineering, The University of Melbourne, Parkville, VIC 3010, Australia.

Department of Chemical Engineering, The University of Melbourne, Parkville, VIC 3010, Australia.

出版信息

J Hazard Mater. 2021 Aug 15;416:125792. doi: 10.1016/j.jhazmat.2021.125792. Epub 2021 Apr 8.

Abstract

Electrochemical regeneration of Granular Activated Carbon is an emerging treatment option to restore adsorption capacity in systems designed to remove organic contaminants from aqueous solutions. The electro-Fenton process is one such electrochemical process and it is reviewed along with other members of its family including Photoelectro-Fenton and Heterogeneous electro-Fenton and electro-Fenton like reactions, for its ability to regenerate Granular Activated Carbons contaminated with organics. The behaviour of critical operating parameter such as pH, current, catalyst concentration and initial contaminant concentration are reviewed to find optimal operating conditions. The relationship between electro-Fenton regeneration and the chemical and physical surface of the carbon is also explored. Understanding regeneration mechanisms and the optimal operating conditions enables these technologies to be used commercially and to be scaled-up and treat contaminated waters more efficiently.

摘要

电再生颗粒活性炭是一种新兴的处理方法,用于恢复设计用于从水溶液中去除有机污染物的系统中的吸附能力。电芬顿工艺就是这样一种电化学工艺,本文对其进行了综述,同时还综述了包括光电芬顿和多相电芬顿以及类芬顿反应在内的其他成员,因为它们都能够再生被有机物污染的颗粒活性炭。综述了关键操作参数(如 pH 值、电流、催化剂浓度和初始污染物浓度)的行为,以找到最佳的操作条件。还探讨了电芬顿再生与活性炭的化学和物理表面之间的关系。了解再生机制和最佳操作条件可以使这些技术在商业上得到应用,并进行放大,从而更有效地处理受污染的水。

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