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通过高级氧化工艺实现染料饱和活性炭的再生:综述

Regeneration of dye-saturated activated carbon through advanced oxidative processes: A review.

作者信息

Santos Danilo Henrique da Silva, Xiao Ye, Chaukura Nhamo, Hill Josephine M, Selvasembian Rangabhashiyam, Zanta Carmem L P Silva, Meili Lucas

机构信息

Laboratório de Eletroquímica Aplicada, Instituto de Química e Biotecnologia, Universidade Federal de Alagoas, UFAL, Maceió, Brazil.

Laboratório de Processos, Centro de Tecnologia, Universidade Federal de Alagoas, UFAL, Maceió, Brazil.

出版信息

Heliyon. 2022 Aug 13;8(8):e10205. doi: 10.1016/j.heliyon.2022.e10205. eCollection 2022 Aug.

Abstract

Activated carbon (AC) is a porous carbon-rich material that is widely used to remove pollutants, such as synthetic dyes, from contaminated water. Although quite efficient, the use of this technology is limited to the ability of the AC to be regenerated and/or reused. Conventional regeneration procedures are inefficient, requiring the development and/or implementation of new approaches. Advanced Oxidative Processes (AOP) have unique properties that result in high efficiency in wastewater treatment. The use of these technologies in the regeneration of AC has gained considerable prominence due to the ability to remove organic pollutants concentrated in the AC. During this process, the oxidizing species produced interact with the substrates adsorbed on the AC, in a non-selective way, mineralizing them and/or reducing their recalcitrance. Although widely used in wastewater treatment, few reviews focus on the use of AOP as AC regeneration technology, causing an insufficient exchange of information and ideas for strategic development in this area. Therefore, in this review, the authors present an overview of the use of some AOP (Photolysis, Peroxidation, Fenton reaction and Advanced electrochemical oxidative processes) when applied in regeneration of dye-saturated AC, including the mechanisms involved in the different processes, the general aspects that affect individual processes and the different methods established to quantify the effectiveness of regeneration.

摘要

活性炭(AC)是一种富含孔隙的碳质材料,广泛用于从受污染的水中去除污染物,如合成染料。尽管该技术相当有效,但其应用仅限于活性炭的再生和/或再利用能力。传统的再生程序效率低下,需要开发和/或实施新的方法。高级氧化工艺(AOP)具有独特的特性,在废水处理中具有高效率。由于能够去除浓缩在活性炭中的有机污染物,这些技术在活性炭再生中的应用已获得相当大的关注。在此过程中,产生的氧化物种与吸附在活性炭上的底物以非选择性方式相互作用,将它们矿化和/或降低其难降解性。尽管高级氧化工艺在废水处理中广泛应用,但很少有综述关注其作为活性炭再生技术的应用,导致该领域战略发展的信息和思想交流不足。因此,在本综述中,作者概述了一些高级氧化工艺(光解、过氧化、芬顿反应和高级电化学氧化工艺)在染料饱和活性炭再生中的应用,包括不同过程涉及的机制、影响各个过程的一般方面以及为量化再生效果而建立的不同方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed55/9404357/d2a407610cdc/gr1.jpg

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