含氯的亚硒酸氯（IV）：强Cl⋅⋅⋅Cl卤键的实例
Oxochloroselenate(IV) with Incorporated {Cl }: The Case of Strong Cl⋅⋅⋅Cl Halogen Bonding.
作者信息
Usoltsev Andrey N, Korobeynikov Nikita A, Kolesov Boris A, Novikov Alexander S, Abramov Pavel A, Sokolov Maxim N, Adonin Sergey A
机构信息
Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090, Novosibirsk, Russia.
Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7-9, 199034, Saint Petersburg, Russia.
出版信息
Chemistry. 2021 Jun 25;27(36):9292-9294. doi: 10.1002/chem.202101024. Epub 2021 May 21.
Reaction of SeO , tetramethylammonium (TMA) chloride, aqueous HCl and Cl yields oxochloroselenate with incorporated Cl units, TMA {Se O Cl }. The main feature of this compound is the strong (up to 3.5 kcal mol , according to DFT calculations) Cl⋅⋅⋅Cl bonding, which is also detected by Raman spectroscopy.
二氧化硒（SeO₂）、四甲基氯化铵（TMA）、盐酸水溶液（HCl）和氯气（Cl₂）反应生成含有氯单元的氯氧化硒酸盐，即四甲基铵盐{SeO₂Cl₂}。该化合物的主要特征是存在强的Cl⋅⋅⋅Cl键（根据密度泛函理论计算，键能高达3.5千卡/摩尔），拉曼光谱也检测到了这种键。
Zotero 插件