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带有2,4,6-三苯基-1,3,5-三嗪核心的芳香树枝状大分子及其光催化性能

Aromatic Dendrimers Bearing 2,4,6-Triphenyl-1,3,5-triazine Cores and Their Photocatalytic Performance.

作者信息

Cyniak Jakub S, Kasprzak Artur

机构信息

Faculty of Chemistry, Warsaw University of Technology, Noakowskiego Str. 3, 00-664 Warsaw, Poland.

出版信息

J Org Chem. 2021 May 7;86(9):6855-6862. doi: 10.1021/acs.joc.1c00039. Epub 2021 Apr 22.

DOI:10.1021/acs.joc.1c00039
PMID:33885288
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8279487/
Abstract

The synthesis of two novel aromatic dendrimers structurally derived from 1,3,5-tri[1,3-diphenyl(phenyl-5-yl)phenyl-4'-yl]benzene and bearing 2,4,6-triphenyl-1,3,5-triazine cores is reported. The obtained dendrimers were used for the OLEDs construction, as well as in the role of innovative photocatalysts for the very efficient and selective oxidation of various benzylamines to respective -benzylidene benzylamines under mild conditions.

摘要

报道了两种新型芳香树枝状大分子的合成，其结构源自1,3,5-三[1,3-二苯基（苯基-5-基）苯基-4'-基]苯，并带有2,4,6-三苯基-1,3,5-三嗪核。所制备的树枝状大分子用于有机发光二极管（OLED）的构建，还可作为创新的光催化剂，在温和条件下将各种苄胺非常高效且选择性地氧化为相应的亚苄基苄胺。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a064/8279487/d0c6f81c18a0/jo1c00039_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a064/8279487/833628d2aa7c/jo1c00039_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a064/8279487/daad8fc2eed6/jo1c00039_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a064/8279487/d0c6f81c18a0/jo1c00039_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a064/8279487/833628d2aa7c/jo1c00039_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a064/8279487/daad8fc2eed6/jo1c00039_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a064/8279487/d0c6f81c18a0/jo1c00039_0003.jpg

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本文引用的文献

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