绿光诱导环加成反应。
Green-light induced cycloadditions.
机构信息
Centre for Materials Science, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD 4000, Australia.
School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD 4000, Australia.
出版信息
Chem Commun (Camb). 2021 Apr 22;57(33):3991-3994. doi: 10.1039/d1cc00340b.
PMID:33885643
Abstract
We introduce a red-shifted tetrazole that is able to undergo efficient nitrile imine-mediated tetrazole-ene cycloaddition (NITEC) under blue and green light irradiation. We provide a detailed wavelength-dependent reactivity map, and employ a number of LEDs for high-conversion small molecule and polymer end-group modification.
摘要
我们介绍了一种红移的四唑，它能够在蓝光和绿光照射下进行有效的腈亚胺介导的四唑-烯环加成反应（NITEC）。我们提供了详细的波长依赖性反应性图谱，并使用了多个 LED 进行高转化率的小分子和聚合物端基修饰。
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