Mechanochromic properties in a mononuclear Cu(I) complex without cuprophilic interactions.
作者信息
Yu Xiao, Li Xiaoyue, Cai Zelun, Sun Lingzhi, Wang Chengbo, Rao Haixia, Wei Chen, Bian Zuqiang, Jin Qionghua, Liu Zhiwei
机构信息
Department of Chemistry, Capital Normal University, Beijing, 100048, China.
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Rare Earth Materials Chemistry and Applications, Beijing Engineering Technology Research Centre of Active Display, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.
出版信息
Chem Commun (Camb). 2021 May 20;57(41):5082-5085. doi: 10.1039/d1cc01229k.
Two polymorphs of Cu[(3,4-bis(diphenylphosphino)thiophene)(bis(pyrazol-1-yl)borohydrate)] (1) were isolated. The blue luminescent crystals have evident mechanochromic luminescent (MCL) properties. Based on photophysical and structural analysis, the pore structure in the blue crystals is considered to be the main reason for the MCL properties.
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