在FeS(CO)中用三苯基膦（PPh）取代羰基（CO）是通过一种新型的FeS中间体进行的。
CO substitution by PPh in FeS(CO) proceeds via a novel FeS intermediate.
作者信息
Zhang Fanjun, Woods Toby J, Rauchfuss Thomas B, Arrigoni Federica, Zampella Giuseppe
机构信息
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273165, China.
出版信息
Chem Commun (Camb). 2021 May 21;57(41):5079-5081. doi: 10.1039/d1cc00956g. Epub 2021 Apr 23.
Abstract
The reaction of FeS(CO) and PPh affords FeS(CO)(PPh) by an unprecedented mechanism involving the intermediacy of SPPh and FeS(CO)(PPh).
摘要
FeS(CO) 与 PPh 的反应通过一种前所未有的机制生成 FeS(CO)(PPh)，该机制涉及 SPPh 和 FeS(CO)(PPh) 作为中间体。
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