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使用滴流床反应器从合成气中生产甲烷。

Methane production from syngas using a trickle-bed reactor setup.

机构信息

Department of Biological and Chemical Engineering, Hangøvej 2, DK-8200 Aarhus N, Denmark.

出版信息

Bioresour Technol. 2021 Aug;333:125183. doi: 10.1016/j.biortech.2021.125183. Epub 2021 Apr 16.

Abstract

Syngas from gasification of waste biomass is a mixture of carbon monoxide (CO), carbon dioxide (CO), and hydrogen (H), which can be utilized for the synthesis of biofuels such as methane (CH). The aim of the study research work was to demonstrate how syngas could be methanated and upgraded to natural gas quality (biomethane) in a fed-batch trickle-bed reactor system using either manure - (AD-M) or sludge-based (AD-WW) inoculum as microbial basis. The methanated syngas had a high concentration of CO and did not fulfil the criteria for natural gas quality biomethane. Further upgrading of syngas to biomethane could be achieved simultaneously in the same reactors by addition of exogenous H resulting in CH concentrations up to 91.0 ± 3.5% (AD-WW) and 95.3 ± 1.0% (AD-M). Microbial analysis indicated that the communities differed between AD-M and AD-WW demonstrating functional redundancy among the microbial communities of different inocula.

摘要

气化废生物质产生的合成气是一氧化碳 (CO)、二氧化碳 (CO) 和氢气 (H) 的混合物,可用于合成甲烷 (CH) 等生物燃料。该研究工作的目的是展示如何在进料分批滴流床反应器系统中,使用粪便基 (AD-M) 或污泥基 (AD-WW) 接种物作为微生物基础,将合成气甲烷化并升级为天然气质量 (生物甲烷)。甲烷化合成气中 CO 浓度很高,不符合天然气质量生物甲烷的标准。通过添加外源 H,可以在相同的反应器中同时将合成气进一步升级为生物甲烷,从而使 CH 浓度达到 91.0 ± 3.5%(AD-WW)和 95.3 ± 1.0%(AD-M)。微生物分析表明,AD-M 和 AD-WW 之间的群落存在差异,表明不同接种物的微生物群落之间存在功能冗余。

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