Xu Xiang, Liu Wei, Luo Xiaoyan, Chen Hongbo, Wei Qingya, Yuan Jun, Zou Yingping
College of Chemistry and Chemical Engineering, Central South University, Changsha, 140083, Hunan, P.R. China.
Chipsemi Semiconductor (Ningbo) Co. Ltd., Shanghai, 201203, P.R. China.
ChemSusChem. 2021 Sep 6;14(17):3428-3448. doi: 10.1002/cssc.202100386. Epub 2021 Jun 26.
In recent years, indoor organic photovoltaics (IOPVs) have attracted increasing attention because of their ability to power microelectronic devices and sensors, especially for the internet of things (IoT). In contrast with silicon-based indoor PV, the IOPVs exhibit better performance due to their tunable bandgap via molecular design, which could achieve a better spectrum matched with the lighting sources. Based on the simulated power conversion efficiency (PCE) in theory, the maximum value can achieve over 50 % under the white LED illumination, which is much higher than the practical top PCE of 31 %, indicating there is room further to improve the performance of IOPVs by various optimization methods. Based on these benefits, the recent progress in IOPVs with different methods was summarizes, and light was shed on the remaining challenges for achieving practical applications in the future. In the end, some guidelines for the development of IOPVs were proposed.
近年来,室内有机光伏(IOPV)因其能够为微电子设备和传感器供电,特别是用于物联网(IoT),而受到越来越多的关注。与基于硅的室内光伏相比,IOPV通过分子设计具有可调节的带隙,因而表现出更好的性能,这可以实现与光源更好的光谱匹配。基于理论模拟的功率转换效率(PCE),在白色LED照明下最大值可以超过50%,这远高于实际最高PCE的31%,表明通过各种优化方法进一步提高IOPV的性能仍有空间。基于这些优点,总结了采用不同方法在IOPV方面的最新进展,并阐明了未来实现实际应用所面临的剩余挑战。最后,提出了一些IOPV发展的指导方针。