二配位碘（I）和银（I）配合物中的亲核碘鎓相互作用（NIIs）
Nucleophilic iodonium interactions (NIIs) in 2-coordinate iodine(I) and silver(I) complexes.
作者信息
Ward Jas S, Frontera Antonio, Rissanen Kari
机构信息
University of Jyvaskyla, Department of Chemistry, Jyväskylä 40014, Finland.
Department of Chemistry, Universitat de les Illes Balears, Crts de Valldemossa km 7.6, Palma de Mallorca Baleares 07122, Spain.
出版信息
Chem Commun (Camb). 2021 May 20;57(41):5094-5097. doi: 10.1039/d1cc01505b.
The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(i) and iodonium (I+) complexes and studying their 15N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(i) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.
通过制备一系列银（I）和碘鎓（I⁺）配合物并研究它们的¹⁵N NMR化学位移，证明了亲核碘鎓相互作用（NIIs）的普遍性。通过X射线晶体学证实了涉及二配位银（I）配合物的NII配合物的第一个实例，并通过DFT计算研究了其亲核性。
Zotero 插件