Markodimitrakis Ioannis E, Sema Dionysios G, Chamakos Nikolaos T, Papadopoulos Periklis, Papathanasiou Athanasios G
School of Chemical Engineering, National Technical University of Athens, 15780, Greece.
Department of Physics, University of Ioannina, Greece and Institute of Materials Science and Computing, University Research Center of Ioannina, Greece.
Soft Matter. 2021 Apr 28;17(16):4335-4341. doi: 10.1039/d0sm02281k.
The electrostatically assisted wettability enhancement of dielectric solid surfaces, commonly termed as electrowetting-on-dielectric (EWOD), facilitates many microfluidic applications due to simplicity and energy efficiency. The application of a voltage difference between a conductive droplet and an insulated electrode substrate, where the droplet sits, is enough for realizing a considerable contact angle change. The contact angle modification is fast and almost reversible; however it is limited by the well-known saturation phenomenon which sets in at sufficiently high voltages. In this work, we experimentally show and computationally support the effect of elasticity and thickness of the dielectric on the onset of contact angle saturation. We found that the effect of elasticity is important especially for dielectric thickness smaller than 10 μm and becomes negligible for thickness above 20 μm. We attribute our findings on the effect of the dielectric thickness on the electric field, as well as on the induced electric stresses distribution, in the vicinity of the three phase contact line. Electric field and electric stresses distribution are numerically computed and support our findings which are of significant importance for the design of soft materials based microfluidic devices.
介电固体表面的静电辅助润湿性增强,通常称为介质上电润湿(EWOD),由于其简单性和能源效率,促进了许多微流体应用。在导电液滴和放置液滴的绝缘电极基板之间施加电压差,就足以实现相当大的接触角变化。接触角的改变快速且几乎可逆;然而,它受到在足够高电压下出现的众所周知的饱和现象的限制。在这项工作中,我们通过实验展示并通过计算支持了电介质的弹性和厚度对接触角饱和起始的影响。我们发现,弹性的影响尤其对于厚度小于10μm的电介质很重要,而对于厚度大于20μm的电介质则可以忽略不计。我们将我们关于电介质厚度对电场以及三相接触线附近感应电应力分布的影响的发现归因于此。电场和电应力分布通过数值计算得出,支持了我们的发现,这些发现对于基于软材料的微流体装置的设计具有重要意义。