Walawalkar Mrinalini G, Pandey Priya, Murugavel Ramaswamy
Department of Chemistry, IIT Bombay, Mumbai, 400076, India.
Angew Chem Int Ed Engl. 2021 Jun 1;60(23):12632-12635. doi: 10.1002/anie.202101770. Epub 2021 Apr 29.
The recent discoveries of both dicationic and monoanionic ferrocene derivatives throw light on the effect of the substituents on the C ring as well as the choice of redox agents and solvent system in the preparation of previously believed to be difficult synthetic targets. These oxidized and reduced forms of ferrocene are of interest to spectroscopists, magnetochemists, and theoreticians.
最近二价阳离子和单阴离子二茂铁衍生物的发现，揭示了取代基对C环的影响，以及在制备以前被认为难以合成的目标物时氧化还原试剂和溶剂体系的选择。二茂铁的这些氧化态和还原态形式引起了光谱学家、磁化学家及理论化学家的兴趣。
