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基于局域表面等离子体共振效应的镧系材料调制发光

Modulated Luminescence of Lanthanide Materials by Local Surface Plasmon Resonance Effect.

作者信息

Liu Jinhua, Wang Qingru, Sang Xu, Hu Huimin, Li Shuhong, Zhang Dong, Liu Cailong, Wang Qinglin, Zhang Bingyuan, Wang Wenjun, Song Feng

机构信息

School of Physical Science and Information Technology, Shandong Provinical Key Laboratory of Optical Communication Science and Technology, Liaocheng University, Liaocheng 252059, China.

School of Physics, Nankai University, Tianjin 300071, China.

出版信息

Nanomaterials (Basel). 2021 Apr 19;11(4):1037. doi: 10.3390/nano11041037.

Abstract

Lanthanide materials have great applications in optical communication, biological fluorescence imaging, laser, and so on, due to their narrow emission bandwidths, large Stokes' shifts, long emission lifetimes, and excellent photo-stability. However, the photon absorption cross-section of lanthanide ions is generally small, and the luminescence efficiency is relatively low. The effective improvement of the lanthanide-doped materials has been a challenge in the implementation of many applications. The local surface plasmon resonance (LSPR) effect of plasmonic nanoparticles (NPs) can improve the luminescence in different aspects: excitation enhancement induced by enhanced local field, emission enhancement induced by increased radiative decay, and quenching induced by increased non-radiative decay. In addition, plasmonic NPs can also regulate the energy transfer between two close lanthanide ions. In this review, the properties of the nanocomposite systems of lanthanide material and plasmonic NPs are presented, respectively. The mechanism of lanthanide materials regulated by plasmonic NPs and the scientific and technological discoveries of the luminescence technology are elaborated. Due to the large gap between the reported enhancement and the theoretical enhancement, some new strategies applied in lanthanide materials and related development in the plasmonic enhancing luminescence are presented.

摘要

镧系材料由于其发射带宽窄、斯托克斯位移大、发射寿命长以及出色的光稳定性,在光通信、生物荧光成像、激光等领域有广泛应用。然而,镧系离子的光子吸收截面通常较小,发光效率相对较低。在许多应用的实施中,有效提高镧系掺杂材料一直是一项挑战。等离子体纳米粒子(NPs)的局域表面等离子体共振(LSPR)效应可以在不同方面改善发光:增强的局域场引起的激发增强、辐射衰减增加引起的发射增强以及非辐射衰减增加引起的猝灭。此外,等离子体NPs还可以调节两个相邻镧系离子之间的能量转移。在这篇综述中,分别介绍了镧系材料与等离子体NPs纳米复合体系的性质。阐述了等离子体NPs调控镧系材料的机制以及发光技术的科学和技术发现。由于报道的增强与理论增强之间存在较大差距,还介绍了一些应用于镧系材料的新策略以及等离子体增强发光的相关进展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0cce/8072723/96fc2e44ea1f/nanomaterials-11-01037-g001.jpg

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