• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

先进碳纳米材料电极中的氢纳米计量学

Hydrogen Nanometrology in Advanced Carbon Nanomaterial Electrodes.

作者信息

Lobo Rui, Alvarez Noe, Shanov Vesselin

机构信息

Laboratory of Nanophysics/Nanotechnology and Energy (N2E), Center of Technology and Systems (CTS-UNINOVA), NOVA School of Science & Technology, FCT-NOVA, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal.

Department of Physics, NOVA School of Science & Technology, FCT-NOVA, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal.

出版信息

Nanomaterials (Basel). 2021 Apr 22;11(5):1079. doi: 10.3390/nano11051079.

DOI:10.3390/nano11051079
PMID:33922071
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8143510/
Abstract

A comparative experimental study between advanced carbon nanostructured electrodes, in similar hydrogen uptake/desorption conditions, is investigated making use of the recent molecular beam-thermal desorption spectrometry. This technique is used for monitoring hydrogen uptake and release from different carbon electrocatalysts: 3D-graphene, single-walled carbon nanotube networks, multi-walled carbon nanotube networks, and carbon nanotube thread. It allows an accurate determination of the hydrogen mass absorbed in electrodes made from these materials, with significant enhancement in the signal-to-noise ratio for trace hydrogen avoiding recourse to ultra-high vacuum procedures. The hydrogen mass spectra account for the enhanced surface capability for hydrogen adsorption in the different types of electrode in similar uptake conditions, and confirm their enhanced hydrogen storage capacity, pointing to a great potential of carbon nanotube threads in replacing the heavier metals or metal alloys as hydrogen storage media.

摘要

利用最近的分子束热脱附光谱法，在相似的氢吸收/解吸条件下，对先进的碳纳米结构电极进行了一项对比实验研究。该技术用于监测不同碳电催化剂（三维石墨烯、单壁碳纳米管网络、多壁碳纳米管网络和碳纳米管线）的氢吸收和释放。它能够精确测定由这些材料制成的电极中吸收的氢质量，显著提高痕量氢的信噪比，而无需采用超高真空程序。氢质谱说明了在相似吸收条件下不同类型电极中氢吸附表面能力的增强，并证实了它们增强的储氢能力，表明碳纳米管线在替代重金属或金属合金作为储氢介质方面具有巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/fee63b57b830/nanomaterials-11-01079-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/ee30366f6eee/nanomaterials-11-01079-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/25d15183283d/nanomaterials-11-01079-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/977c5be9976f/nanomaterials-11-01079-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/6c1f2f01a720/nanomaterials-11-01079-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/77289a6d6b9c/nanomaterials-11-01079-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/cd664a165c65/nanomaterials-11-01079-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/fee63b57b830/nanomaterials-11-01079-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/ee30366f6eee/nanomaterials-11-01079-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/25d15183283d/nanomaterials-11-01079-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/977c5be9976f/nanomaterials-11-01079-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/6c1f2f01a720/nanomaterials-11-01079-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/77289a6d6b9c/nanomaterials-11-01079-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/cd664a165c65/nanomaterials-11-01079-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4103/8143510/fee63b57b830/nanomaterials-11-01079-g007.jpg

相似文献

1
Hydrogen Nanometrology in Advanced Carbon Nanomaterial Electrodes.先进碳纳米材料电极中的氢纳米计量学
Nanomaterials (Basel). 2021 Apr 22;11(5):1079. doi: 10.3390/nano11051079.
2
Hydrogen Uptake and Release in Carbon Nanotube Electrocatalysts.碳纳米管电催化剂中的氢吸收与释放
Nanomaterials (Basel). 2021 Apr 10;11(4):975. doi: 10.3390/nano11040975.
3
Molecular Beam-Thermal Desorption Spectrometry (MB-TDS) Monitoring of Hydrogen Desorbed from Storage Fuel Cell Anodes.分子束-热脱附光谱法（MB-TDS）监测储氢燃料电池阳极脱附的氢气
Materials (Basel). 2012 Feb 6;5(2):248-257. doi: 10.3390/ma5020248.
4
Electrochemical hydrogen storage in single-walled carbon nanotube paper.单壁碳纳米管纸中的电化学储氢
J Nanosci Nanotechnol. 2006 Mar;6(3):713-8. doi: 10.1166/jnn.2006.083.
5
pH-sensitive loading/releasing of doxorubicin using single-walled carbon nanotube and multi-walled carbon nanotube: A molecular dynamics study.利用单壁碳纳米管和多壁碳纳米管进行 pH 敏感的阿霉素载入/释放：分子动力学研究。
Comput Methods Programs Biomed. 2020 Apr;186:105210. doi: 10.1016/j.cmpb.2019.105210. Epub 2019 Nov 14.
6
Molecular beam-thermal hydrogen desorption from palladium.钯表面分子束热氢脱附
Rev Sci Instrum. 2010 Apr;81(4):043103. doi: 10.1063/1.3385686.
7
Carbon nanotube and graphene-based bioinspired electrochemical actuators.基于碳纳米管和石墨烯的仿生电化学致动器。
Adv Mater. 2014 Feb;26(7):1025-43. doi: 10.1002/adma.201303432. Epub 2013 Dec 12.
8
Integrated single-walled carbon nanotube/microfluidic devices for the study of the sensing mechanism of nanotube sensors.用于研究纳米管传感器传感机制的集成单壁碳纳米管/微流控装置
J Phys Chem B. 2005 Jul 21;109(28):13406-8. doi: 10.1021/jp0525686.
9
Carbon nanotubes as solid-phase extraction sorbents prior to atomic spectrometric determination of metal species: a review.碳纳米管作为固相萃取吸附剂在原子光谱法测定金属物种之前的应用：综述。
Anal Chim Acta. 2012 Oct 24;749:16-35. doi: 10.1016/j.aca.2012.09.001. Epub 2012 Sep 10.
10
Electrochemical hydrogen evolution of multi-walled carbon nanotube/micro-hybrid composite decorated with Ni nanoparticles as catalyst through electroless deposition process.通过化学镀沉积工艺，在负载 Ni 纳米粒子的多壁碳纳米管/微混合复合材料上实现电化学析氢。
Mater Sci Eng C Mater Biol Appl. 2013 Aug 1;33(6):3173-9. doi: 10.1016/j.msec.2013.03.038. Epub 2013 Apr 1.

引用本文的文献

1
Nanophysics Is Boosting Nanotechnology for Clean Renewable Energy.纳米物理学正在推动用于清洁可再生能源的纳米技术发展。
Materials (Basel). 2024 Nov 1;17(21):5356. doi: 10.3390/ma17215356.

本文引用的文献

1
An Overview of the Recent Progress in Modifications of Carbon Nanotubes for Hydrogen Adsorption.用于氢吸附的碳纳米管修饰的最新进展综述
Nanomaterials (Basel). 2020 Feb 1;10(2):255. doi: 10.3390/nano10020255.
2
Diffusion controlled multilayer electrocatalysts via graphene oxide nanosheets of varying sizes.通过不同尺寸氧化石墨烯纳米片实现扩散控制的多层电催化剂。
Nanoscale. 2018 Aug 30;10(34):16159-16168. doi: 10.1039/c8nr02883d.
3
Molecular Beam-Thermal Desorption Spectrometry (MB-TDS) Monitoring of Hydrogen Desorbed from Storage Fuel Cell Anodes.
分子束-热脱附光谱法（MB-TDS）监测储氢燃料电池阳极脱附的氢气
Materials (Basel). 2012 Feb 6;5(2):248-257. doi: 10.3390/ma5020248.
4
Environmental Applications of 2D Molybdenum Disulfide (MoS) Nanosheets.二维二硫化钼（MoS）纳米片的环境应用。
Environ Sci Technol. 2017 Aug 1;51(15):8229-8244. doi: 10.1021/acs.est.7b01466. Epub 2017 Jul 17.
5
Highly hydrogen-sensitive thermal desorption spectroscopy system for quantitative analysis of low hydrogen concentration (∼1 × 10 atoms/cm) in thin-film samples.用于定量分析薄膜样品中低氢浓度（约1×10个原子/立方厘米）的高氢敏热脱附光谱系统。
Rev Sci Instrum. 2017 May;88(5):053103. doi: 10.1063/1.4982255.
6
Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts.使用 Pt/α-MoC 催化剂从水和甲醇中低温制氢。
Nature. 2017 Apr 6;544(7648):80-83. doi: 10.1038/nature21672. Epub 2017 Mar 22.
7
Flexible Micro-Supercapacitor Based on Graphene with 3D Structure.基于三维结构石墨烯的柔性微型超级电容器。
Small. 2017 Mar;13(10). doi: 10.1002/smll.201603114. Epub 2017 Jan 5.
8
Recent Progress in Cobalt-Based Heterogeneous Catalysts for Electrochemical Water Splitting.电化学水分解用钴基多相催化剂的最新进展。
Adv Mater. 2016 Jan 13;28(2):215-30. doi: 10.1002/adma.201502696. Epub 2015 Nov 9.
9
Carbon-Based Sorbents with Three-Dimensional Architectures for Water Remediation.用于水修复的具有三维结构的碳基吸附剂。
Small. 2015 Jul 15;11(27):3319-36. doi: 10.1002/smll.201403729. Epub 2015 Mar 23.
10
Ultra high vacuum high precision low background setup with temperature control for thermal desorption mass spectroscopy (TDA-MS) of hydrogen in metals.用于金属中氢的热脱附质谱分析（TDA-MS）的具有温度控制功能的超高真空高精度低本底装置。
Talanta. 2015 May;136:108-13. doi: 10.1016/j.talanta.2015.01.014. Epub 2015 Jan 19.