Usman Muhammad, Helal Aasif, Abdelnaby Mahmoud M, Alloush Ahmed M, Zeama Mostafa, Yamani Zain H
Center of Research Excellence in Nanotechnology (CENT), King Fahd University of Petroleum & Minerals (KFUPM), KFUPM Box 5040, Dhahran, 31261, Saudi Arabia.
King Abdulaziz City for Science and Technology - Technology Innovation Center on Carbon Capture and Sequestration (KACST-TIC on CCS) at, KFUPM, Dhahran, 31261, Saudi Arabia.
Chem Rec. 2021 Jul;21(7):1771-1791. doi: 10.1002/tcr.202100030. Epub 2021 May 5.
Among thousands of known metal-organic frameworks (MOFs), the University of Oslo's MOF (UiO-66) exhibits unique structure topology, chemical and thermal stability, and intriguing tunable properties, that have gained incredible research interest. This paper summarizes the structural advancement of UiO-66 and its role in CO capture, separation, and transformation into chemicals. The first part of the review summarizes the fast-growing literature related to the CO capture reported by UiO-66 during the past ten years. The second part provides an overview of various advancements in UiO-66 membranes in CO purification. The third part describes the role of UiO-66 and its composites as catalysts for CO conversion into useful products. Despite many achievements, significant challenges associated with UiO-66 are addressed, and future perspectives are comprehensively presented to forecast how UiO-66 might be used further for CO management.
在数千种已知的金属有机框架（MOF）中，奥斯陆大学的MOF（UiO - 66）展现出独特的结构拓扑、化学和热稳定性以及引人入胜的可调谐特性，这些特性引发了极大的研究兴趣。本文总结了UiO - 66的结构进展及其在CO捕获、分离以及转化为化学品方面的作用。综述的第一部分总结了过去十年中与UiO - 66报道的CO捕获相关的快速增长的文献。第二部分概述了UiO - 66膜在CO净化方面的各种进展。第三部分描述了UiO - 66及其复合材料作为将CO转化为有用产品的催化剂的作用。尽管取得了许多成就，但文中也探讨了与UiO - 66相关的重大挑战，并全面呈现了未来展望，以预测UiO - 66如何进一步用于CO管理。
