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聚合物铅笔芯石墨在光子辐照下的热释光动力学参数研究。

Studies of thermoluminescence kinetic parameters of polymer pencil lead graphite under photon exposures.

机构信息

Centre for Applied Physics and Radiation Technologies, School of Engineering and Technology, Sunway University, 47500, Bandar Sunway, Selangor, Malaysia.

Centre for Applied Physics and Radiation Technologies, School of Engineering and Technology, Sunway University, 47500, Bandar Sunway, Selangor, Malaysia.

出版信息

Appl Radiat Isot. 2021 Aug;174:109757. doi: 10.1016/j.apradiso.2021.109757. Epub 2021 May 5.

Abstract

This study analysed thermoluminescence (TL) glow curves of the polymer pencil lead graphite (PPLG) due to its potential applications in radiation dosimetry. The TL glow curves provide information on the physical parameters of the defects participating in luminescence process. The glow curves for different diameters PPLG samples were obtained with varying temperature from 50 to 300 °C, at a fixed heating rate of 10 °Cs. A number of methods (initial rise, peak shape and curve fitting) were used to fit the TL glow peaks of the PPLG samples obtained under photon dose of 200 Gy. From the fitted TL signals, the trap parameters such as the order of kinetics, the activation energy, the frequency factor, etc. for the individual peaks were numerically determined. The lifetimes of TL process were calculated assuming the first-order kinetics. The results are compared among the different methods adopted in this study. Implications about the possible results in glow curve deconvolution are discussed.

摘要

本研究分析了聚合物铅笔芯石墨(PPLG)的热释光(TL)发光曲线,因为它在辐射剂量学中有潜在的应用。TL 发光曲线提供了参与发光过程的缺陷的物理参数信息。在固定的升温速率为 10°C/s 的情况下,通过从 50°C 到 300°C 的不同温度,获得了不同直径 PPLG 样品的 TL 发光曲线。使用了多种方法(初始上升、峰形和曲线拟合)来拟合在光子剂量为 200Gy 下获得的 PPLG 样品的 TL 发光峰。从拟合的 TL 信号中,数值确定了各个峰的动力学阶数、激活能、频率因子等陷阱参数。假设一阶动力学,计算了 TL 过程的寿命。比较了本研究中采用的不同方法的结果。讨论了在发光曲线反卷积中可能得到的结果的含义。

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