A novel dispersive magnetic solid phase microextraction using ionic liquid-coated amino silanized magnetic graphene oxide nanocomposite for high efficient separation/preconcentration of toxic ions from shellfish samples.

A novel dispersive magnetic solid phase microextraction (d-MSPE) method using ionic liquid-coated amino silanized magnetic graphene oxide (MGO@SiO-APTES-IL) as adsorbent has been established for enriching and extracting lead(II), copper(II) and cadmium(II) in shellfish samples. The novel nanocomposite was proved synthesized successfully by various characterization technologies. Parameters that could affect the recoveries of target ions were investigated and optimized focusing on adsorption and desorption using Box-Behnken design of response surface methodology (BBD-RSM). The limits of detection (LODs) for three target heavy metal ions were 2.42, 3.36, 3.75 ng L, respectively. Additionally, the maximum adsorption capacities of the nanocomposite for target ions were 251.23, 138.51, 159.31 mg g at 298 K, respectively, the nanoadsorbent can be regenerated without significant adsorption capacities loss for four times. These observations revealed that the novel nanocomposite can be used as an excellent adsorbent for separation and preconcentration of the target ions.