合成可行的碱土金属配合物M(Cp)（M = Ca、Sr、Ba）中的过渡金属化学
Transition metal chemistry in synthetically viable alkaline earth complexes M(Cp) (M = Ca, Sr, Ba).
作者信息
Huo Bin, Sun Rui, Jin Bo, Hu Lingfei, Bian Jian-Hong, Guan Xiao-Ling, Yuan Caixia, Lu Gang, Wu Yan-Bo
机构信息
Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province, Institute of Molecular Science, Shanxi University, Taiyuan 030006, People's Republic of China.
School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People's Republic of China.
出版信息
Chem Commun (Camb). 2021 Jun 10;57(47):5806-5809. doi: 10.1039/d1cc01753e.
We predicted the stable alkaline earth complexes M(Cp)3- (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the bonding behaviour of transition metals by participating in bonding with the π orbitals of Cp ligands using their d orbitals.
我们预测了稳定的碱土金属配合物M(Cp)₃⁻（M = Ca、Sr、Ba；Cp = 环戊二烯基），其中M中心处于其稳定的 +2氧化态，并通过使用其d轨道与Cp配体的π轨道参与成键来模拟过渡金属的成键行为。
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