Varela Lucas, Téllez Gabriel, Trizac Emmanuel
Université Paris-Saclay, CNRS, LPTMS, 91405 Orsay, France.
Universidad de los Andes, Bogotá, Colombia.
Phys Rev E. 2021 Apr;103(4-1):042603. doi: 10.1103/PhysRevE.103.042603.
We consider a one-dimensional model allowing analytical derivation of the effective interactions between two charged colloids. We evaluate exactly the partition function for an electroneutral salt-free suspension with dielectric jumps at the colloids' position. We derive a contact relation with the pressure that shows there is like-charge attraction, whether or not the counterions are confined between the colloids. In contrast to the homogeneous dielectric case, there is the possibility for the colloids to attract despite the number of counterions (N) being even. The results are shown to recover the mean-field prediction in the limit N→∞.
我们考虑一个一维模型,该模型允许对两个带电胶体之间的有效相互作用进行解析推导。我们精确评估了在胶体位置存在介电跃变的电中性无盐悬浮液的配分函数。我们推导了与压力的接触关系,结果表明无论抗衡离子是否被限制在胶体之间,都存在同电荷吸引。与均匀介电情况不同,即使抗衡离子数量(N)为偶数,胶体也有可能相互吸引。结果表明,在N→∞的极限情况下,该结果恢复了平均场预测。