High energy density and extremely stable supercapacitors based on carbon aerogels with 100% capacitance retention up to 65,000 cycles.

In terms of ideal future energy storage systems, besides the always-pursued energy/power characteristics, long-term stability is crucial for their practical application. Here, we report a facile and sustainable strategy for the scalable fabrication of carbon aerogels with three-dimensional interconnected nanofiber networks and rationally designed hierarchical porous structures, which are based on the carbonization of bacterial cellulose assisted by the soft template of Zn-1,3,5-benzenetricarboxylic acid. As binder-free electrodes, they deliver a fundamentally enhanced specific capacitance of 352 F ⋅ g at 1 A ⋅ g in a wide potential window (1.2 V, 6 M KOH) in comparison with those of bacterial cellulose-derived carbons (178 F ⋅ g) and most activated carbons (usually lower than 250 F ⋅ g). The as-assembled supercapacitors exhibit an ultrahigh capacitance of 297 F ⋅ g at 1 A ⋅ g, remarkable energy density (14.83 Wh ⋅ kg at 0.60 kW ⋅ kg), and extremely high stability, with 100% capacitance retention for up to 65,000 cycles at 6 A ⋅ g, representing their superior energy storage performance when compared with that of state-of-the-art supercapacitors of commercial activated carbons and biomass-derived analogs.