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高温对AISI 1020钢上银-氧化钴-二氧化钛(Ag/CoO/TiO₂)纳米复合涂层耐腐蚀性的影响

Effects of elevated temperature on the corrosion resistance of silver-cobalt oxide-titanium dioxide (Ag/CoO/TiO) nanocomposites coating on AISI 1020.

作者信息

Ibrahim Mohammed, Agboola Joseph B, Abdulkareem Saka A, Adedipe Oyewole, Tijani Jimoh O

机构信息

Department of Mechanical Engineering, Federal University of Technology, Minna, Nigeria.

Metallurgical and Materials Engineering Department, University of Lagos, Lagos, Nigeria.

出版信息

Sci Rep. 2021 May 25;11(1):10921. doi: 10.1038/s41598-021-90272-w.

Abstract

The effects of temperature on corrosion resistance of Silver-Cobalt oxide and Titanium Dioxide (Ag/CoO/TiO) nanocomposite coated AISI 1020 in a high-temperature environment was investigated. The Ag, CoO and TiO nanoparticles were individually produced by mixing the salt precursors with extract of Piptadeniastrum Africana leaf under the optimized synthesis conditions. The nanocomposite was produced by mixing Ag, CoO and TiO nanoparticles (NPs) in equal proportions to constitute 75 wt% of the composite. 10 wt% epoxy resin and its hardener in the ratio (1:1) were added to serve as the binder, while 15 wt% of CNT was introduced to serve as support. The produced Ag/CoO/TiO nanocomposite was coated on the surface of mild steel (AISI 1020) by the dipping method. The coated samples were heated in a muffle furnace to 35, 100, 200, and 300 °C. Microstructural evolution of the coatings was investigated using X-ray diffraction, scanning electron microscopy and energy dispersive spectrometer. The corrosion resistance of the coated and heated and un-heated steel samples was determined using the potentiodynamic polarization method. The results show that Ag/CoO/TiO nanocomposite coated sample cured at 100 °C exhibited the highest corrosion resistance of 195.12 Ω.

摘要

研究了温度对高温环境下涂覆有银 - 氧化钴和二氧化钛(Ag/CoO/TiO)纳米复合材料的AISI 1020钢耐腐蚀性的影响。在优化的合成条件下,通过将盐前驱体与非洲猴耳环叶提取物混合,分别制备了Ag、CoO和TiO纳米颗粒。通过将Ag、CoO和TiO纳米颗粒(NPs)按等比例混合以构成复合材料的75 wt%来制备纳米复合材料。添加10 wt%比例为(1:1)的环氧树脂及其固化剂作为粘结剂,同时引入15 wt%的碳纳米管作为支撑体。采用浸渍法将制备的Ag/CoO/TiO纳米复合材料涂覆在低碳钢(AISI 1020)表面。将涂覆后的样品在马弗炉中加热至35、100、200和300℃。使用X射线衍射、扫描电子显微镜和能谱仪研究涂层的微观结构演变。采用动电位极化法测定涂覆及加热和未加热钢样品的耐腐蚀性。结果表明,在100℃固化的Ag/CoO/TiO纳米复合材料涂覆样品表现出最高的耐腐蚀性,为195.12Ω。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8525/8149452/8aec70cda8ed/41598_2021_90272_Fig2_HTML.jpg

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