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1

Synthesis of [16,16,19(-2)H3; 19(-3)H]19-oxo-androst-4-ene-3,17-dione.[16,16,19(-2)H3; 19(-3)H]19-氧代雄甾-4-烯-3,17-二酮的合成

J Chromatogr. 1988 May 25;440:415-20. doi: 10.1016/s0021-9673(00)94545-x.

2

Synthesis of 3 beta,16 beta,19-trihydroxyandrost-5-en-17-one and 16 beta,19-dihydroxyandrost-4-ene-3,17-dione and their 19-oxo derivatives.3β,16β,19 - 三羟基雄甾 - 5 - 烯 - 17 - 酮、16β,19 - 二羟基雄甾 - 4 - 烯 - 3,17 - 二酮及其19 - 氧代衍生物的合成

Steroids. 1990 Sep;55(9):383-9. doi: 10.1016/0039-128x(90)90095-s.

3

Synthesis of 16 alpha-hydroxyandrost-4-ene-3,17,19-trione and 3 beta, 16 alpha-dihydroxyandrost-5-ene-17,19-dione; potential intermediates of estriol biosynthesis.16α-羟基雄甾-4-烯-3,17,19-三酮和3β,16α-二羟基雄甾-5-烯-17,19-二酮的合成；雌三醇生物合成的潜在中间体。

Chem Pharm Bull (Tokyo). 1990 Jul;38(7):2040-2. doi: 10.1248/cpb.38.2040.

4

An efficient synthesis of 5alpha-androst-1-ene-3,17-dione.5α-雄甾-1-烯-3,17-二酮的高效合成。

Steroids. 2006 Dec;71(13-14):1088-90. doi: 10.1016/j.steroids.2006.09.008. Epub 2006 Nov 22.

5

Synthesis of deuterium-labeled 16 alpha,19-dihydroxy C19 steroids as internal standards for gas chromatography-mass spectrometry.氘标记的16α,19 - 二羟基C19甾体作为气相色谱 - 质谱联用内标物的合成

Chem Pharm Bull (Tokyo). 1992 Oct;40(10):2759-63. doi: 10.1248/cpb.40.2759.

6

Mechanism for aromatase inactivation by a suicide substrate, androst-4-ene-3,6,17-trione. The 4 beta, 5 beta-epoxy-19-oxo derivative as a reactive electrophile irreversibly binding to the active site.自杀底物雄甾-4-烯-3,6,17-三酮使芳香化酶失活的机制。4β,5β-环氧-19-氧代衍生物作为反应性亲电试剂不可逆地结合到活性位点。

Biochem Pharmacol. 1996 Oct 25;52(8):1253-9. doi: 10.1016/0006-2952(96)00479-0.

7

The chemistry of 9 alpha-hydroxysteroids. 3. Methods for selective formation and dehydrations of 17 beta-cyano-9 alpha,17 alpha-dihydroxyandrost-4-en-3-one.9α-羟基甾体的化学。3. 17β-氰基-9α,17α-二羟基雄甾-4-烯-3-酮的选择性形成及脱水方法。

Steroids. 1990 Mar;55(3):109-13. doi: 10.1016/0039-128x(90)90005-v.

8

Biotransformation of (+)-androst-4-ene-3,17-dione.（+）-雄甾-4-烯-3,17-二酮的生物转化

Nat Prod Res. 2004 Dec;18(6):529-35. doi: 10.1080/14786410310001620628.

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Androst-5-ene-7,17-dione: a novel class of suicide substrate of aromatase.雄甾-5-烯-7,17-二酮：一种新型的芳香化酶自杀底物。

Biochem Biophys Res Commun. 1992 Jul 15;186(1):32-9. doi: 10.1016/s0006-291x(05)80771-5.

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Inhibition and inactivation of estrogen synthetase (aromatase) by fluorinated substrate analogues.氟化底物类似物对雌激素合成酶（芳香化酶）的抑制与失活作用。

Biochemistry. 1982 May 25;21(11):2773-8. doi: 10.1021/bi00540a030.

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[16,16,19(-2)H3; 19(-3)H]19-氧代雄甾-4-烯-3,17-二酮的合成

Synthesis of [16,16,19(-2)H3; 19(-3)H]19-oxo-androst-4-ene-3,17-dione.

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