Rahmati Morteza, Yeganeh Golan, Esmaeili Hossein
Acta Chim Slov. 2019 Dec;66(4):888-898.
In this paper, the adsorption potential of activated carbon prepared by Ziziphus spina-christi lotus leaf for the removal of sulfate from aqueous solution was investigated. To this end, the effect of different parameters such as pH, contact time, temperature, adsorbent concentration, and initial sulfate ion concentration was investigated. The results indicated that the highest adsorption efficiency (84.5%) was obtained at pH 6, adsorbent concentration of 5 g/L, sulfate ion concentration of 20 ppm, 65 min and temperature of 45 °C. Also, the adsorption equilibrium study showed that the adsorption process follows the Langmuir isotherm model with the maximum adsorption capacity of 9.3 mg/g. In addition, the thermodynamic study showed that the adsorption process on the activated carbon surface was spontaneous. Moreover, the adsorption process was exothermic accompanied by a decrease in irregularity. Furthermore, the adsorption kinetic study indicated that the adsorption process follows the pseudo-second-order kinetic model.
本文研究了由酸枣荷叶制备的活性炭对水溶液中硫酸根的吸附潜力。为此,研究了不同参数如pH值、接触时间、温度、吸附剂浓度和初始硫酸根离子浓度的影响。结果表明,在pH值为6、吸附剂浓度为5 g/L、硫酸根离子浓度为20 ppm、接触时间为65分钟和温度为45℃时,吸附效率最高(84.5%)。此外,吸附平衡研究表明,吸附过程遵循朗缪尔等温线模型,最大吸附容量为9.3 mg/g。另外,热力学研究表明,活性炭表面的吸附过程是自发的。而且,吸附过程是放热的,伴随着不规则性的降低。此外,吸附动力学研究表明,吸附过程遵循准二级动力学模型。