Hao Yu-Mei
Acta Chim Slov. 2021 Mar;68(1):102-108.
A mononuclear copper(II) complex, [CuL] (1), and a phenolato-bridged trinuclear zinc(II) complex, [Zn3Cl2L2(DMF)2] (2), where L is the deprotonated form of N,N'-bis(4-bromosalicylidene)propane-1,3-diamine (H2L), have been prepared and characterized by elemental analyses, IR and UV-Vis spectroscopy, and single crystal X-ray diffraction. The Cu atom in complex 1 is in square planar coordination, while the terminal and central Zn atoms in complex 2 are in square pyramidal and octahedral coordination, respectively. The antibacterial activities of the complexes have been tested on the bacteria Staphylococcus aureus and Escherichia coli, and the yeast Candida parapsilosis.
已制备出一种单核铜（II）配合物[CuL]（1）和一种酚氧基桥联的三核锌（II）配合物[Zn3Cl2L2(DMF)2]（2），其中L为N,N'-双（4-溴水杨醛）丙烷-1,3-二胺（H2L）的去质子化形式，并通过元素分析、红外光谱和紫外可见光谱以及单晶X射线衍射对其进行了表征。配合物1中的铜原子呈平面正方形配位，而配合物2中的末端锌原子和中心锌原子分别呈四方锥和八面体配位。已对金黄色葡萄球菌、大肠杆菌和近平滑假丝酵母测试了这些配合物的抗菌活性。
