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活化过程及金属氧化物添加(CaO、MgO、SrO)对天然沸石在酯交换反应中催化性能及物理化学性质的影响

The Effect of the Activation Process and Metal Oxide Addition (CaO, MgO, SrO) on the Catalytic and Physicochemical Properties of Natural Zeolite in Transesterification Reaction.

作者信息

Mierczynski Pawel, Szkudlarek Lukasz, Chalupka Karolina, Maniukiewicz Waldemar, Wahono Satriyo K, Vasilev Krasimir, Szynkowska-Jozwik Malgorzata I

机构信息

Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.

Research Division for Natural Product Technology, Indonesian Institutes of Sciences, Jl. Jogja-Wonosari km 32, Gading, Playen, Gunungkidul, Yogyakarta 55861, Indonesia.

出版信息

Materials (Basel). 2021 May 6;14(9):2415. doi: 10.3390/ma14092415.

DOI:10.3390/ma14092415
PMID:34066469
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8124687/
Abstract

This work provides valuable information about unexplored catalytic systems tested in the transesterification reaction of vegetable oil with methanol. It was demonstrated that natural zeolite treatment leads to enhanced catalytic activity and yield of biodiesel production. The activation of the catalytic material in a mixture of 5% H-95% Ar resulted in an improvement of the values of the TG conversion and fatty acid methyl esters (FAME) yield. In addition, it was proven that the incorporation of CaO, MgO and SrO oxides onto the natural zeolite surface improves the TG conversion and FAME yield values in the transesterification reaction.

摘要

这项工作提供了有关在植物油与甲醇的酯交换反应中测试的未探索催化体系的宝贵信息。结果表明,天然沸石处理可提高生物柴油生产的催化活性和产率。在5%H-95%Ar的混合物中对催化材料进行活化,提高了甘油三酯(TG)转化率和脂肪酸甲酯(FAME)产率的值。此外,已证明在天然沸石表面引入CaO、MgO和SrO氧化物可提高酯交换反应中的TG转化率和FAME产率值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/00060855efad/materials-14-02415-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/92f064789acb/materials-14-02415-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/c586de7dedd8/materials-14-02415-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/605fee5672a3/materials-14-02415-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/22301676af2f/materials-14-02415-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/f3b783766999/materials-14-02415-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/f7ebf88fe0ab/materials-14-02415-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/00060855efad/materials-14-02415-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/92f064789acb/materials-14-02415-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/c586de7dedd8/materials-14-02415-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/605fee5672a3/materials-14-02415-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/22301676af2f/materials-14-02415-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/f3b783766999/materials-14-02415-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/f7ebf88fe0ab/materials-14-02415-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03c7/8124687/00060855efad/materials-14-02415-g006.jpg

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本文引用的文献

1
Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on Natural Zeolite.天然沸石负载的单金属铂、钯、钌和银催化剂上的生物柴油生产
Materials (Basel). 2020 Dec 24;14(1):48. doi: 10.3390/ma14010048.
2
Biodiesel production--current state of the art and challenges.生物柴油生产——当前技术水平与挑战
J Ind Microbiol Biotechnol. 2008 May;35(5):421. doi: 10.1007/s10295-008-0312-2. Epub 2008 Jan 18.