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注塑成型短麻纤维增强热塑性复合材料的界面改性、吸水性及力学性能

Interface Modification, Water Absorption Behaviour and Mechanical Properties of Injection Moulded Short Hemp Fiber-Reinforced Thermoplastic Composites.

作者信息

Manaia João P, Manaia Ana

机构信息

Laboratory for Wear, Testing & Materials (LED&MAT), Instituto Pedro Nunes, Rua Pedro Nunes, 3030-199 Coimbra, Portugal.

出版信息

Polymers (Basel). 2021 May 18;13(10):1638. doi: 10.3390/polym13101638.

Abstract

The effects of maleic anhydride, stearic acid and water absorption on the physical and flexural properties of injection moulded short hemp fiber-reinforced thermoplastic composites were investigated, in order to understand the suitability of these materials for outdoor applications. The water absorption, diffusion mechanisms and kinetics of composites were evaluated by immersing the specimens in distilled water at 23 °C. Flexural fracture surface morphologies were investigated in order to compare the results of flexural tests with qualitative morphological observations. The process of water absorption was found to follow the Fickian mode of diffusion. Flexural properties (Ef and σfm) were affected by the water absorption. The addition of maleic anhydride and stearic acid enhanced the resistance to water absorption of composites and resulted in a slight increase of flexural properties of composites based on a high-density polyethylene (HDPE) matrix. The reduction in flexural properties induced by the degradation of matrix-fiber interfacial bonding due to water absorbed was confirmed by scanning electron microscopy analysis.

摘要

研究了马来酸酐、硬脂酸和吸水性对注塑成型短麻纤维增强热塑性复合材料物理性能和弯曲性能的影响,以了解这些材料在户外应用中的适用性。通过将试样浸泡在23℃的蒸馏水中来评估复合材料的吸水性、扩散机制和动力学。研究弯曲断裂表面形态,以便将弯曲试验结果与定性形态观察结果进行比较。发现吸水过程遵循菲克扩散模式。弯曲性能(Ef和σfm)受吸水性影响。马来酸酐和硬脂酸的添加增强了复合材料的吸水性,并导致基于高密度聚乙烯(HDPE)基体的复合材料弯曲性能略有增加。扫描电子显微镜分析证实,由于吸水导致基体-纤维界面结合降解,从而引起弯曲性能降低。

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