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MWCNTs-早强型水泥基砂浆复合材料的力学和电学性能: CNTs 的分散及其化学外加剂的影响。

Mechanical and electrical properties of MWCNTs - high early strength cement - mortars composite: Dispersion of CNTs and effect of chemical admixtures.

机构信息

Universidad Técnica Particular de Loja, 110150, Loja, San Cayetano Alto, Calle París, Loja, 110150 Provincia de Loja, Ecuador.

Universidad Nacional de Chimborazo, Facultad de Ingeniería, Av. Antonio José de Sucre, Riobamba, 060150 Riobamba, Provincia de Chimborazo, Ecuador.

出版信息

An Acad Bras Cienc. 2021 May 31;93(3):e20200924. doi: 10.1590/0001-3765202120200924. eCollection 2021.

Abstract

The objectives of this research were to study (1) the dispersion of MWCNTs in an aqueous system by three commercial admixtures (CAds) for concrete, and (2) the effect of CAds and MWCNTs on indirect tensile strength and electrical conductivity of MWCNTs-high early strength (HE) cement-mortar composites. To achieve the objectives, we dispersed MWCNTs in an aqueous system with (1) hydroxylated polymers-based water reducing plasticizer (HPs), a nonionic compound, (2) Naphthalene based superplasticizer (SNF), an anionic compound, and (3) calcium chloride-based accelerating agent (CC) a neutral amphoteric salt. We prepared a total of 242 samples grouped in three sets: (1) Plain mortar [PM] (water + HE cement + Sand), (2) [PM+CAd], and (3) [PM+CAd+MWCNTs]. The three CAds dispersed MWCNTs in an aqueous solution. The CC and HPs admixtures have a two-time bigger dispersing power than the SNF. They demand half of SNF's ultrasound energy for optimal dispersion. Although the SNF (anionic) based superplasticizer resulted incompatible with the HE cement, it improved the indirect tensile strength of [PM+SNF+MWCNTs] composite. In contrast, the CC (amphoteric) based accelerating agent was compatible with the HE cement; the CC adsorption on the MWCNTs surface favors an improvement in the electrical conductivity of [PM+CAd+MWCNTs] composite.

摘要

本研究的目的是

(1)通过三种商用混凝土外加剂(CAds)研究 MWCNTs 在水基中的分散性;(2)研究 CAds 和 MWCNTs 对 MWCNTs-早强(HE)水泥浆体复合材料间接拉伸强度和电导率的影响。为实现上述目标,我们将 MWCNTs 分散在水性体系中:(1)含有羟化聚合物的减水剂(HPs),一种非离子化合物;(2)萘系高效减水剂(SNF),一种阴离子化合物;(3)氯化钙基加速剂(CC),一种中性两性盐。我们总共制备了 242 个样品,分为三组:(1)普通水泥砂浆[PM](水+HE 水泥+砂);(2)[PM+CAd];(3)[PM+CAd+MWCNTs]。这三种 CAds 可在水溶液中分散 MWCNTs。CC 和 HPs 外加剂对 MWCNTs 的分散能力比 SNF 大两倍。它们需要 SNF 超声能量的一半才能达到最佳分散效果。虽然基于 SNF(阴离子)的高效减水剂与 HE 水泥不相容,但它提高了[PM+SNF+MWCNTs]复合材料的间接拉伸强度。相比之下,基于 CC(两性)的加速剂与 HE 水泥相容;CC 在 MWCNTs 表面的吸附有利于提高[PM+CAd+MWCNTs]复合材料的电导率。

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