通过一种在焦点处涉及手性识别的自组装方法构建Janus树枝状大分子。

Construction of Janus dendrimers through a self-assembly approach involving chiral discrimination at a focal point.

作者信息

Zhou John, Cole Ashley M, Menuey Elizabeth M, Kilway Kathleen V, Moteki Shin A

机构信息

Department of Chemistry, University of Missouri-Kansas City, 5100 Rockhill Road, Kansas City, Missouri 64110-2499, USA.

出版信息

Chem Commun (Camb). 2021 Jun 29;57(52):6404-6407. doi: 10.1039/d1cc01973b.

DOI:10.1039/d1cc01973b

PMID:34086017

Abstract

A strategy to build Janus dendrimers via the chirality-directed self-assembly of heteroleptic Zn(ii) BOX complexes is reported. The method allows quantitative synthesis of Janus dendrimers in situ without the need for purifications. Each dendritic domain of the Janus dendrimers can be recycled upon disassembly at the focal point.

摘要

报道了一种通过手性导向的杂配锌（II）BOX配合物自组装来构建Janus树枝状大分子的策略。该方法能够原位定量合成Janus树枝状大分子，无需纯化。Janus树枝状大分子的每个树枝状区域在焦点处拆卸后均可循环利用。