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基于阿拉伯胶、明胶、壳聚糖和β-环糊精的多功能微球土壤改良剂的制备与应用研究

Study on preparation and application of a multifunctional microspheric soil conditioner based on Arabic gum, gelatin, chitosan and β-cyclodextrin.

作者信息

Li Yakun, Rao Pinhua, Wang Jincheng, Song Shiqiang, Wang Runkai, Liu Shihui, Che Lei

机构信息

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China.

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China.

出版信息

Int J Biol Macromol. 2021 Jul 31;183:1851-1860. doi: 10.1016/j.ijbiomac.2021.05.205. Epub 2021 Jun 1.

Abstract

All kinds of soil conditioners have been used to improve soil quality. The application of many traditional soil conditioners was limited by single performance. In this study, a novel multifunctional microspheric soil conditioner was prepared based on Arabic gum, gelatin, chitosan and β-cyclodextrin. Arabic gum and gelatin (AG-GL) microspheric carriers, which could load ferrous sulfate (FS), were synthesized via complex coagulation method. The AG-GL(FS) microspheres were covered by chitosan quaternary ammonium salt (CQAS) through single coagulation method. And β-cyclodextrin (β-CD) was used as the outermost shell to improve chemical stability of the soil conditioner by saturated solution method. Finally, the novel multifunctional microspheric soil conditioner AG-GL/CQAS/β-CD-FS was obtained and characterized by Fourier transform infrared spectroscopy, thermogravimetric analyzer, polarizing microscope, scanning electron microscope and particle size analyzer. The novel soil conditioner shows good nutrient slowly-releasing, water retention, heavy metal ions adsorption and antibacterial performances with the particle size of 14-17 μm and high thermal decomposition temperature, which has the potential application in improving soil quality.

摘要

人们已使用各种土壤改良剂来改善土壤质量。许多传统土壤改良剂的应用受到单一性能的限制。在本研究中,基于阿拉伯胶、明胶、壳聚糖和β-环糊精制备了一种新型多功能微球形土壤改良剂。通过复合凝聚法合成了可负载硫酸亚铁(FS)的阿拉伯胶和明胶(AG-GL)微球载体。通过单凝聚法用壳聚糖季铵盐(CQAS)包覆AG-GL(FS)微球。并采用饱和溶液法将β-环糊精(β-CD)用作最外层壳以提高土壤改良剂的化学稳定性。最终得到新型多功能微球形土壤改良剂AG-GL/CQAS/β-CD-FS,并通过傅里叶变换红外光谱、热重分析仪、偏光显微镜、扫描电子显微镜和粒度分析仪对其进行了表征。该新型土壤改良剂具有良好的养分缓释、保水、重金属离子吸附和抗菌性能,粒径为14 - 17μm,热分解温度高,在改善土壤质量方面具有潜在应用价值。

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