水电解原理以及钴基、镍基和铁基氧化物用于析氧反应的研究进展

Principles of Water Electrolysis and Recent Progress in Cobalt-, Nickel-, and Iron-Based Oxides for the Oxygen Evolution Reaction.

作者信息

Yu Mingquan, Budiyanto Eko, Tüysüz Harun

机构信息

Department of Heterogeneous Catalysis, Max-Planck-Institute für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470, Mülheim an der Ruhr, Germany.

出版信息

Angew Chem Int Ed Engl. 2022 Jan 3;61(1):e202103824. doi: 10.1002/anie.202103824. Epub 2021 Jul 21.

Abstract

Water electrolysis that results in green hydrogen is the key process towards a circular economy. The supply of sustainable electricity and availability of oxygen evolution reaction (OER) electrocatalysts are the main bottlenecks of the process for large-scale production of green hydrogen. A broad range of OER electrocatalysts have been explored to decrease the overpotential and boost the kinetics of this sluggish half-reaction. Co-, Ni-, and Fe-based catalysts have been considered to be potential candidates to replace noble metals due to their tunable 3d electron configuration and spin state, versatility in terms of crystal and electronic structures, as well as abundance in nature. This Review provides some basic principles of water electrolysis, key aspects of OER, and significant criteria for the development of the catalysts. It provides also some insights on recent advances of Co-, Ni-, and Fe-based oxides and a brief perspective on green hydrogen production and the challenges of water electrolysis.

摘要

产生绿色氢气的水电解是迈向循环经济的关键过程。可持续电力的供应和析氧反应(OER)电催化剂的可用性是大规模生产绿色氢气过程的主要瓶颈。人们已经探索了各种各样的OER电催化剂,以降低过电位并加快这种缓慢的半反应的动力学。基于钴、镍和铁的催化剂因其可调的3d电子构型和自旋状态、晶体和电子结构的多样性以及自然界中的丰富储量,被认为是替代贵金属的潜在候选物。本综述提供了水电解的一些基本原理、OER的关键方面以及催化剂开发的重要标准。它还提供了关于钴、镍和铁基氧化物的最新进展的一些见解,以及对绿色氢气生产和水电解挑战的简要展望。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7376/9291824/e18b9021cc8f/ANIE-61-0-g001.jpg

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