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热解锯末、煤和石蜡共热解过程中的协同作用评估。动力学和热力学数据集。

Evaluation of synergy during co-pyrolysis of torrefied sawdust, coal and paraffin. A kinetic and thermodynamic dataset.

作者信息

Florentino-Madiedo L, Vega M F, Díaz-Faes E, Barriocanal C

机构信息

Instituto de Ciencia y Tecnología del Carbono, INCAR-CSIC, Francisco Pintado Fe, 26, 33010 Oviedo. Spain.

出版信息

Data Brief. 2021 May 27;37:107170. doi: 10.1016/j.dib.2021.107170. eCollection 2021 Aug.

Abstract

This article aims to clarify and expand the information published in the article , which evaluate kinetically and thermodynamically the existence of synergies during the co-pyrolysis of binary and ternary blends of coal, torrefied pine sawdust and paraffin. These materials were selected because they have been used before in the preparation of briquettes for the steel industry with good results. In order to facilitate the understanding and reproducibility of the main article, the following descriptions, dataset and figures have been provided: description and formulation of iso-conversional methods, some TGA curves and the standard deviation of the TG analysis, the activation energy of all the raw materials and their blends at different level of conversion using Friedman, Kissinger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO) methods, as well as, the linear plots for their calculations for the KAS and FWO models; also the thermodynamic parameters for pyrolysis of all the samples studied and the theoretical and experimental plots for prediction of solid state reaction mechanism using Criado method of several weights of paraffin are include.

摘要

本文旨在阐明并扩展已发表文章中的信息,该文章对煤、烘焙松木锯末和石蜡的二元及三元混合物共热解过程中协同作用的存在进行了动力学和热力学评估。选择这些材料是因为它们之前已用于钢铁行业型煤的制备,且效果良好。为便于理解和重现主要文章,提供了以下描述、数据集和图表:等转化率方法的描述和公式、一些热重分析(TGA)曲线及TG分析的标准偏差、使用弗里德曼(Friedman)、基辛格-赤平-ose(KAS)和弗林-沃尔-小泽(FWO)方法在不同转化率水平下所有原料及其混合物的活化能,以及KAS和FWO模型计算的线性图;还包括所有研究样品热解的热力学参数,以及使用克里亚多(Criado)方法对几种石蜡重量预测固态反应机理的理论和实验图。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1d/8209234/1f73c5d552e1/gr1.jpg

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