Hg(TeO)(SO)：一种从d金属化合物中探索出的具有新颖结构和大双折射的新型硫酸碲酸盐。
Hg(TeO)(SO): a new sulfate tellurite with a novel structure and large birefringence explored from d metal compounds.
作者信息
Li Peng-Fei, Hu Chun-Li, Gong Ya-Ping, Kong Fang, Mao Jiang-Gao
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
出版信息
Chem Commun (Camb). 2021 Jul 15;57(57):7039-7042. doi: 10.1039/d1cc02494a.
Our exploration of novel inorganic solids with large birefringence in the d10 Metal-Te4+-SO42- system afforded four new sulfate tellurites, Ga2(TeO3)(SO4)(OH)2, In2(TeO3)2(SO4)(H2O), Zn4(Te3O7)2(SO4)2(H2O) and Hg3(Te3O8)(SO4). Notably, Hg3(Te3O8)(SO4) exhibits the largest birefringence at 532 nm (0.184) and 1064 nm (0.166) among the reported metal sulfate tellurites.
我们对d10金属-Te4+-SO42-体系中具有大双折射的新型无机固体进行了探索，得到了四种新的硫酸碲酸盐，即Ga2(TeO3)(SO4)(OH)2、In2(TeO3)2(SO4)(H2O)、Zn4(Te3O7)2(SO4)2(H2O)和Hg3(Te3O8)(SO4)。值得注意的是，在已报道的金属硫酸碲酸盐中，Hg3(Te3O8)(SO4)在532 nm（0.184）和1064 nm（0.166）处表现出最大的双折射。
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