• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

采用氧桥连三芳基硼受体的用于高效深蓝色电致发光的穿空间电荷转移树枝状大分子。

Through-space charge transfer dendrimers employing oxygen-bridged triarylboron acceptors for efficient deep-blue electroluminescence.

作者信息

Du Baoyun, Wang Xingdong, Chen Fan, Yang Qingqing, Shao Shiyang, Wang Lixiang, Jing Xiabin, Wang Fosong

机构信息

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China.

出版信息

Chem Commun (Camb). 2021 Jul 20;57(58):7144-7147. doi: 10.1039/d1cc02311j.

DOI:10.1039/d1cc02311j
PMID:34180922
Abstract

Through-space charge transfer dendrimers consisting of dendritic triacridan donors and oxygen-bridged triarylboron acceptors are demonstrated to exhibit deep-blue thermally activated delayed fluorescence with the state-of-the-art external quantum efficiency of 14.6% for electroluminescence by a solution process.

摘要

由树枝状三吖啶供体和氧桥连三芳基硼受体组成的穿空间电荷转移树枝状大分子,通过溶液法制备的电致发光器件表现出深蓝色热激活延迟荧光,其外量子效率达到了目前最先进的14.6%。

相似文献

1
Through-space charge transfer dendrimers employing oxygen-bridged triarylboron acceptors for efficient deep-blue electroluminescence.采用氧桥连三芳基硼受体的用于高效深蓝色电致发光的穿空间电荷转移树枝状大分子。
Chem Commun (Camb). 2021 Jul 20;57(58):7144-7147. doi: 10.1039/d1cc02311j.
2
π-Stacked Donor-Acceptor Dendrimers for Highly Efficient White Electroluminescence.用于高效白色电致发光的π-堆积供体-受体树枝状大分子
Angew Chem Int Ed Engl. 2021 Jul 19;60(30):16585-16593. doi: 10.1002/anie.202104145. Epub 2021 Jun 17.
3
Synthesis and Electroluminescent Properties of Through-Space Charge Transfer Polymers Containing Acridan Donor and Triarylboron Acceptors.含吖啶供体和三芳基硼受体的空间电荷转移聚合物的合成及电致发光性能
Front Chem. 2019 Dec 10;7:854. doi: 10.3389/fchem.2019.00854. eCollection 2019.
4
Through-Space Charge-Transfer Polynorbornenes with Fixed and Controllable Spatial Alignment of Donor and Acceptor for High-Efficiency Blue Thermally Activated Delayed Fluorescence.具有供体和受体固定且可控空间排列的用于高效蓝色热激活延迟荧光的空间电荷转移聚降冰片烯。
Angew Chem Int Ed Engl. 2020 Nov 2;59(45):20174-20182. doi: 10.1002/anie.202008912. Epub 2020 Aug 28.
5
Developing Through-Space Charge Transfer Polymers as a General Approach to Realize Full-Color and White Emission with Thermally Activated Delayed Fluorescence.开发空间电荷转移聚合物作为实现具有热激活延迟荧光的全色和白色发射的通用方法。
Angew Chem Int Ed Engl. 2019 Jun 17;58(25):8405-8409. doi: 10.1002/anie.201902264. Epub 2019 May 17.
6
Impact of Boron Acceptors on the TADF Properties of -Donor-Appended Triarylboron Emitters.硼受体对供体连接的三芳基硼发射体热激活延迟荧光性质的影响。
Front Chem. 2020 Jun 24;8:538. doi: 10.3389/fchem.2020.00538. eCollection 2020.
7
Efficient and Stable Deep-Blue Fluorescent Organic Light-Emitting Diodes Employing a Sensitizer with Fast Triplet Upconversion.采用具有快速三重态上转换敏化剂的高效稳定深蓝色荧光有机发光二极管。
Adv Mater. 2020 May;32(19):e1908355. doi: 10.1002/adma.201908355. Epub 2020 Apr 6.
8
Triarylboron-Based Fluorescent Organic Light-Emitting Diodes with External Quantum Efficiencies Exceeding 20 .基于三芳基硼的荧光有机发光二极管,外量子效率超过 20%。
Angew Chem Int Ed Engl. 2015 Dec 7;54(50):15231-5. doi: 10.1002/anie.201508270. Epub 2015 Nov 13.
9
Thermally Activated Delayed Fluorescence and Aggregation Induced Emission with Through-Space Charge Transfer.热激活延迟荧光和通过空间电荷转移的聚集诱导发射。
J Am Chem Soc. 2017 Apr 5;139(13):4894-4900. doi: 10.1021/jacs.7b00873. Epub 2017 Mar 27.
10
Phosphine-Oxide-Balanced Intra- and Interchain Through-Space Charge Transfer in Thermally Activated Delayed Fluorescence Polymers: Beyond 30% External Quantum Efficiency.热激活延迟荧光聚合物中膦氧化物平衡的链内和链间空间电荷转移:超越30%的外量子效率
Adv Mater. 2023 Oct;35(41):e2304103. doi: 10.1002/adma.202304103. Epub 2023 Sep 5.

引用本文的文献

1
Rethinking boron's role in intramolecular charge transfer: from an acceptor to a donor-acceptor regulator.重新审视硼在分子内电荷转移中的作用:从受体到给体-受体调节剂。
Chem Sci. 2025 May 9. doi: 10.1039/d5sc01916h.
2
Acceptor-Donor-Acceptor -Stacking Boosts Intramolecular Through-Space Charge Transfer towards Efficient Red TADF and High-Performance OLEDs.受体-给体-受体堆积促进分子内空间电荷转移,实现高效红色热激活延迟荧光和高性能有机发光二极管。
Research (Wash D C). 2022 Jun 24;2022:9892802. doi: 10.34133/2022/9892802. eCollection 2022.
3
Advances in Blue Exciplex-Based Organic Light-Emitting Materials and Devices.
基于蓝色激基复合物的有机发光材料与器件的进展
Front Chem. 2022 Jul 12;10:952116. doi: 10.3389/fchem.2022.952116. eCollection 2022.
4
Narrowband blue emission with insensitivity to the doping concentration from an oxygen-bridged triarylboron-based TADF emitter: nondoped OLEDs with a high external quantum efficiency up to 21.4.基于氧桥联三芳基硼的热活化延迟荧光(TADF)发光体的窄带蓝光发射对掺杂浓度不敏感:具有高达21.4的高外量子效率的非掺杂有机发光二极管。
Chem Sci. 2022 Feb 21;13(12):3402-3408. doi: 10.1039/d2sc00329e. eCollection 2022 Mar 24.