Xie Qiongyi, Ou Hong, Yang Qingyun, Lin Xiaoming, Zeb Akif, Li Kang, Chen Xinli, Ma Guozheng
Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry, South China Normal University, Guangzhou 510006, China.
Dalton Trans. 2021 Jul 21;50(28):9669-9684. doi: 10.1039/d1dt01482j.
In recent years, metal-organic frameworks (MOFs) have been widely used in the field of electrochemical energy storage and conversion because of their excellent properties, such as high specific surface area, adjustable pore size, high porosity, structural diversity, and functional controllability. This paper reviews the applications of metal-organic framework-derived composites such as nitrogen-doped carbon, transition metal sulfides, transition metal selenides, transition metal phosphides and metal selenium compound modifications in potassium ion batteries (PIBs) as anode electrode materials. A variety of MOF-derived composites with different structures and morphologies based on several types of ligands, including 2-methylimidazole, aromatic carboxylic acids, and ferricyanide, have been discussed. Moreover, the current challenges faced by MOF-derived materials and possible countermeasures are proposed.
近年来,金属有机框架材料(MOFs)因其具有高比表面积、可调节孔径、高孔隙率、结构多样性和功能可控性等优异性能,在电化学储能与转换领域得到了广泛应用。本文综述了氮掺杂碳、过渡金属硫化物、过渡金属硒化物、过渡金属磷化物和金属硒化合物修饰等金属有机框架衍生复合材料作为钾离子电池(PIBs)负极材料的应用。基于包括2-甲基咪唑、芳香羧酸和铁氰化物在内的几种配体,讨论了多种具有不同结构和形貌的MOF衍生复合材料。此外,还提出了MOF衍生材料目前面临的挑战及可能的应对措施。