University of Zagreb, Faculty of Chemical Engineering and Technology, Marulićev trg 19, HR-10000, Zagreb, Croatia.
University of Zagreb, Faculty of Chemical Engineering and Technology, Marulićev trg 19, HR-10000, Zagreb, Croatia.
J Environ Manage. 2021 Oct 1;295:113133. doi: 10.1016/j.jenvman.2021.113133. Epub 2021 Jun 25.
The aim of this study was to investigate the usefulness of a membrane hybrid process for the treatment of real textile wastewater (TWW) and its potential reuse in the dyeing of cotton knitted fabric (DCF) process. To determine a suitable pretreatment, sand filtration, coagulation, and UF hollow fiber (UF-HF) were compared on a laboratory scale in terms of turbidity, color, and total organic carbon (TOC). Here, UF-HF provided the best removal results of 93.6%, 99.0%, and 29.0%, respectively. The second stage involves the study of UF flat sheet membranes (5, 10, 20, and 50 kDa). The 5 kDa membrane provided the best permeate quality according to the chemical oxygen demand (COD), turbidity, TOC, conductivity, and color by 54.5%, 83.9%, 94.2%, and 45.7-83.3%, respectively. The final step was treatment with nanofiltration (NF) and reverse osmosis (RO) and these effluents were reused for dyeing. Finally, the effluents from UF-HF/5 kDa UF/RO (Scenario 1) and UF-HF/5 kDa UF/NF (Scenario 2) were analyzed for turbidity, COD, TOC, biological oxygen demand, conductivity, hardness, anions and cations, and color. Both scenarios provided high removal results of 76.3-83.5%, 94.6-97.7%, 88.5-99%, 95.4-98.0%, 59.2-99.0%, 88.7-98.7%, 60.7-99.1%, and 80.0-100%, respectively. They also satisfied the DCF tests compared to the standard DCF samples. The innovative aspect of this research is as follows: 1) the complete analysis of hybrid membrane separation processes for the purpose of reuse of treated textile wastewater and 2) the proposal of a new criterion for reuse for DCF.
本研究旨在探讨一种膜混合工艺在处理实际纺织废水(TWW)及其在棉针织织物(DCF)染色过程中的潜在再利用方面的有效性。为了确定合适的预处理方法,在实验室规模上比较了砂滤、混凝和 UF 中空纤维(UF-HF)在浊度、颜色和总有机碳(TOC)方面的效果。结果表明,UF-HF 的去除率分别达到了 93.6%、99.0%和 29.0%。第二阶段研究了 UF 平板膜(5、10、20 和 50 kDa)。根据化学需氧量(COD)、浊度、TOC、电导率和颜色,5 kDa 膜的透过液质量最好,去除率分别为 54.5%、83.9%、94.2%和 45.7-83.3%。最后一步是采用纳滤(NF)和反渗透(RO)处理,这些出水再用于染色。最后,分析了 UF-HF/5 kDa UF/RO(方案 1)和 UF-HF/5 kDa UF/NF(方案 2)的出水的浊度、COD、TOC、生物需氧量、电导率、硬度、阴离子和阳离子以及颜色。两个方案的去除率均高达 76.3-83.5%、94.6-97.7%、88.5-99%、95.4-98.0%、59.2-99.0%、88.7-98.7%、60.7-99.1%和 80.0-100%,且出水均满足 DCF 测试标准。本研究的创新之处在于:1)全面分析了混合膜分离工艺,以实现处理后的纺织废水的再利用;2)提出了用于 DCF 的再利用新准则。