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土壤中灭多威的高变异性可以解释其在环境中的持久性和迁移性。

Highly variable soil dissipation of metaldehyde can explain its environmental persistence and mobility.

机构信息

Fera Science Ltd., York Biotech Campus, Sand Hutton, York, YO41 1LZ, UK; School of Engineering, Newcastle University, NE1 7RU, Newcastle upon Tyne, UK.

Fera Science Ltd., York Biotech Campus, Sand Hutton, York, YO41 1LZ, UK.

出版信息

Chemosphere. 2021 Nov;283:131165. doi: 10.1016/j.chemosphere.2021.131165. Epub 2021 Jun 14.

Abstract

There are increasing concerns about the hazard posed to drinking water resources by persistent, mobile, and toxic (PMT) substances in the environment. For example, the extensive use of metaldehyde-based molluscicide to control slug populations in agricultural fields has frequently led to pollution of surface waters and contamination of drinking water at levels exceeding the statutory limit. Regulatory environmental fate assessments and studies in the literature did not predict that metaldehyde would be persistent in the environment, contrary to observations from monitoring schemes. To understand the reasons for this disparity, this study conducted a suite of degradation experiments, covering different soil types and environmentally realistic conditions in Northern Europe, and generated a distribution of DT values for metaldehyde to examine whether degradation rates are underestimated by current risk assessments. The results were found to vary, showing DT values ranging from 3.0 to 4150 days, which indicated that metaldehyde had the potential to become persistent. Lack of prior metaldehyde exposure, high moisture content, low temperature, and locally high metaldehyde concentration under pellets were identified as high-risk conditions for low pesticide biodegradation in UK soils.

摘要

人们越来越关注环境中持久性、移动性和毒性(PMT)物质对饮用水资源造成的危害。例如,广泛使用聚乙醛类杀螺剂来控制农田中的蛞蝓种群,这经常导致地表水受到污染,饮用水受到污染,超过法定限量。监管环境 Fate 评估和文献中的研究并没有预测到聚乙醛在环境中具有持久性,这与监测计划中的观察结果相反。为了了解造成这种差异的原因,本研究进行了一系列降解实验,涵盖了北欧不同的土壤类型和现实环境条件,并生成了聚乙醛的 DT 值分布,以检验当前风险评估是否低估了降解速率。结果发现存在差异,显示 DT 值范围从 3.0 到 4150 天,这表明聚乙醛有可能具有持久性。在英国土壤中,缺乏先前的聚乙醛暴露、高含水量、低温以及颗粒下局部高浓度的聚乙醛被确定为农药生物降解率低的高风险条件。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1722/8434416/c926006bef4b/ga1.jpg

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