Stawarz Marcin, Dojka Malwina
Department of Foundry Engineering, Silesian University of Technology, 7 Towarowa Street, 44-100 Gliwice, Poland.
Materials (Basel). 2021 Jun 4;14(11):3067. doi: 10.3390/ma14113067.
Continuous improvement in the quality of castings is especially important since a cast without defects is a more competitive product due to its longer lifecycle and cheaper operation. Producing quality castings requires comprehensive knowledge of their production, crystallization process, and chemical composition. The crystallization of alloyed ductile iron (without the addition of magnesium) with oxide bifilm inclusions is discussed. These inclusions reduce the quality of the castings, but they are a catalyst for the growth of spheroidal graphite that crystallizes in their vicinity. The research was carried out for cast iron with a highly hyper-eutectic composition. Scanning electron microscopy and EDS analysis were used in the research. A detailed analysis of the chemical composition was also carried out based on the spectrometric method, weight method, etc. Based on the obtained results, a model of spheroidal graphite crystallization near bifilm inclusions was proposed. The surface of the analyzed graphite particles was smooth, which suggests a primary crystallization process. The phenomenon of simple graphite and bifilm segregation towards the heat center of the castings was also documented.
铸件质量的持续改进尤为重要,因为无缺陷的铸件因其更长的生命周期和更低的运营成本而更具竞争力。生产高质量铸件需要全面了解其生产、结晶过程和化学成分。本文讨论了含有氧化双膜夹杂物的合金球墨铸铁(不添加镁)的结晶过程。这些夹杂物会降低铸件质量,但它们是在其附近结晶的球状石墨生长的催化剂。该研究针对具有高过共晶成分的铸铁进行。研究中使用了扫描电子显微镜和能谱分析。还基于光谱法、重量法等对化学成分进行了详细分析。根据所得结果,提出了双膜夹杂物附近球状石墨结晶的模型。分析的石墨颗粒表面光滑,这表明是一次结晶过程。还记录了简单石墨和双膜向铸件热中心偏析的现象。