Trigoura Leslie, Xing Yalan, Chauhan Bhanu P S
Department of Chemistry, William Paterson University of New Jersey, 300 Pompton Road, Wayne, NJ 07470, USA.
Engineered Nanomaterials Laboratory, Department of Chemistry, William Paterson University of New Jersey, 300 Pompton Road, Wayne, NJ 07470, USA.
Molecules. 2021 Jun 9;26(12):3525. doi: 10.3390/molecules26123525.
In this review, we present an assessment of recent advances in alkyne functionalization reactions, classified according to different classes of recyclable catalysts. In this work, we have incorporated and reviewed the activity and selectivity of recyclable catalytic systems such as polysiloxane-encapsulated novel metal nanoparticle-based catalysts, silica-copper-supported nanocatalysts, graphitic carbon-supported nanocatalysts, metal organic framework (MOF) catalysts, porous organic framework (POP) catalysts, bio-material-supported catalysts, and metal/solvent free recyclable catalysts. In addition, several alkyne functionalization reactions have been elucidated to demonstrate the success and efficiency of recyclable catalysts. In addition, this review also provides the fundamental knowledge required for utilization of green catalysts, which can combine the advantageous features of both homogeneous (catalyst modulation) and heterogeneous (catalyst recycling) catalysis.
在本综述中，我们根据不同类别的可回收催化剂，对炔烃官能团化反应的最新进展进行了评估。在这项工作中，我们纳入并综述了可回收催化体系的活性和选择性，这些体系包括聚硅氧烷封装的新型金属纳米颗粒基催化剂、二氧化硅-铜负载的纳米催化剂、石墨碳负载的纳米催化剂、金属有机框架（MOF）催化剂、多孔有机框架（POP）催化剂、生物材料负载的催化剂以及无金属/无溶剂的可回收催化剂。此外，还阐述了几个炔烃官能团化反应，以证明可回收催化剂的成功与效率。此外，本综述还提供了利用绿色催化剂所需的基础知识，绿色催化剂可兼具均相催化（催化剂调控）和多相催化（催化剂回收）的优势。
