Influence of calcination temperature on photocatalytic HOproductivity of hierarchical porous ZnO microspheres.

Photocatalytic production of HOfrom water and atmospheric oxygen has been recognized as a green and sustainable chemical process, due to the abundance of raw materials and sustainable solar energy. Herein, flower-like hierarchical ZnO microspheres were prepared by hydrothermal method followed by calcination at different temperatures, and their photocatalytic performance in HOproduction was examined under simulated sunlight irradiation. The calcination temperature plays a vital role in the structure, morphology, and surface area of the final ZnO products as well as their optical and electrochemical properties, which are determining factors in their photocatalytic activity. The ZnO calcined at 300 °C (Zn-300) exhibits the highest activity and optimal stability, showing productivity of 2793mol lwithin 60 min of irradiation, which was 6.5 times higher than that of uncalcined ZnO precursor. The remarkable photocatalytic activity is attributed to enhanced light utilization, large surface area, abundant exposed active sites, improved separation efficiency, and prolonged carrier lifespan. Moreover, the results from cycling experiments indicate the as-prepared ZnO samples exhibit good stability and long-time performance. This work provides useful information for the preparation of hierarchical ZnO photocatalysts.