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中国西南贵州省煤田区矿井水的水文地球化学特征及质量评价。

Hydrogeochemical Characteristics and Quality Assessment of Mine Water in Coalfield Area, Guizhou Province, Southwest China.

机构信息

College of Resources and Environmental Engineering, Guizhou University, Guiyang, 550025, China.

Key Laboratory of Karst Georesources and Environment, Ministry of Education, Guiyang, 550025, China.

出版信息

Bull Environ Contam Toxicol. 2021 Dec;107(6):1087-1094. doi: 10.1007/s00128-021-03322-4. Epub 2021 Jul 8.

Abstract

Coal resources are widely distributed in Guizhou province, China and environmental pollution caused by coal mining is becoming increasingly serious, especially mine drainage. A total of 120 mine water samples collected from different coalfields were analyzed to investigate the hydrogeochemical characteristics and assess the water quality for drinking, domestic, and irrigative purposes. Water samples had a pH of 1.90-9.12 and most of them were acidic or weakly acidic. Total dissolved solids (TDS) ranged from 254 to 13,944 mg/L and correlated closely with the electrical conductivity (EC). The coal mine drainage of Guizhou was characterized typically by low pH value, high Fe and SO concentration, which were mainly attributed to oxidative weathering of pyrite. The most dominant type for abandoned coal-mine drainage was Ca-Mg-SO, while that of the underground drainage for active mine were mainly Na-SO and Na-HCO because of high concentration of Na from the dissolution of evaporites and clastic rocks. High concentration of the TDS, SO, Fe, Mn, et al. made it unsuitable for drinking and domestic use, but part of the coal mine drainage could be used for irrigation at some sites.

摘要

贵州省煤炭资源丰富,采煤造成的环境污染日益严重,尤其是矿井水。本研究共采集了 120 个来自不同矿区的矿井水样,分析了其水文地球化学特征,并评估了其饮用水、生活用水和灌溉用水水质。水样的 pH 值为 1.90-9.12,呈弱酸性或酸性。总溶解性固体(TDS)含量为 254-13944mg/L,与电导率(EC)密切相关。贵州煤矿排水的特点是 pH 值低、Fe 和 SO 浓度高,这主要归因于黄铁矿的氧化作用。废弃煤矿排水以 Ca-Mg-SO 为主,而地下排水则以 Na-SO 和 Na-HCO 为主,这是由于蒸发岩和碎屑岩的溶解作用导致 Na 浓度升高所致。高浓度的 TDS、SO、Fe、Mn 等使得这些水样不适合饮用和生活用水,但部分煤矿排水在某些地方可用于灌溉。

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