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由两种噪声引起的克莱默斯势垒穿越问题的解决方案:热噪声和泊松白噪声。

Solution to the Kramers barrier crossing problem caused by two noises: Thermal noise and Poisson white noise.

作者信息

Gera Tarun, Sebastian K L

机构信息

Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, Karnataka, India.

出版信息

J Chem Phys. 2021 Jul 7;155(1):014902. doi: 10.1063/5.0056506.

Abstract

We consider the escape of a particle trapped in a metastable potential well and acted upon by two noises. One of the noises is thermal and the other is Poisson white noise, which is non-Gaussian. Using path integral techniques, we find an analytic solution to this generalization of the classic Kramers barrier crossing problem. Using the "barrier climbing" path, we calculate the activation exponent. We also derive an approximate expression for the prefactor. The calculated results are compared with the simulations, and a good agreement between the two is found. Our results show that, unlike in the case of thermal noise, the rate depends not just on the barrier height but also on the shape of the whole barrier. A comparison between the simulations and the theory also shows that a better approximation for the prefactor is needed for agreement for all values of the parameters.

摘要

我们考虑一个被困在亚稳势阱中并受到两种噪声作用的粒子的逃逸问题。其中一种噪声是热噪声,另一种是泊松白噪声,它是非高斯的。利用路径积分技术,我们找到了经典克莱默斯势垒穿越问题这种推广形式的解析解。通过“翻越势垒”路径,我们计算了活化指数。我们还推导了前置因子的近似表达式。将计算结果与模拟结果进行比较,发现两者吻合良好。我们的结果表明,与热噪声情况不同,速率不仅取决于势垒高度,还取决于整个势垒的形状。模拟结果与理论之间的比较还表明,为了使所有参数值都能达成一致,需要对前置因子进行更好的近似。

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