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污水和污水污泥处理过程中纤维状微塑料(微纤维)的循环。

Circulation of fibrous microplastic (microfiber) in sewage and sewage sludge treatment processes.

机构信息

Osaka City Research Center of Environmental Science, Osaka, Japan.

Osaka City Research Center of Environmental Science, Osaka, Japan.

出版信息

Sci Total Environ. 2021 Nov 15;795:148873. doi: 10.1016/j.scitotenv.2021.148873. Epub 2021 Jul 5.

Abstract

The fate of microplastics (MPs) in the sewage treatment process has been investigated worldwide, and novel results have been reported; few studies have also clarified the fate of MPs in the sewage sludge treatment process. Although most MPs in sewage are transferred to sludge, some flow back from the sludge treatment process to the sewage treatment process. Therefore, throughout the sewage treatment plant, the removal rate of MPs may increase via a countermeasure during the sludge treatment process. In this study, samples obtained from sewage and sewage sludge treatments were used to degrade organic matter with hydrogen peroxide. Water sample particles were trapped on Ni filters with 20-μm-sized pores, dried at room temperature and then the MPs were detected and identified by FTIR microscopy. Note that sludge samples were treated with hydrogen peroxide and separated by specific gravity using NaI solution. The concentration of MPs per unit volume was then calculated and the MPs load was estimated using flow rates of water and sludge. Subsequently, we clarified the fate of MPs with sizes of 20 μm or greater in a sewage treatment plant. When the MPs load in the influent sewage is 100%, 12% of the MPs were found to return to the sewage treatment process via the sidestream of the sludge treatment process. Per this observation, it was made evident that MPs are in fact circulating throughout the sewage and sludge treatment processes. MPs in the sidestream mainly consisted of the effluent from the sludge concentration process, and most MPs were thought to be fibrous polyethylene terephthalate (fibrous MPs, i.e. microfibers [MFs]). The results show that MFs circulate throughout the sewage and sludge treatment processes, and for effectively increasing the removal rate of MPs, the removal of MFs proves correspondingly effective during the sludge treatment process.

摘要

已对全球范围内污水厂处理工艺中微塑料(MPs)的命运进行了研究,并有新的结果报告;但鲜有研究阐明了 MPs 在污水厂污泥处理工艺中的命运。尽管污水中的大多数 MPs 都转移到了污泥中,但也有一些从污泥处理工艺回流到污水厂处理工艺。因此,通过在污泥处理工艺过程中采取对策,整个污水厂处理工艺中 MPs 的去除率可能会增加。在本研究中,使用从污水和污泥处理中获得的样品,用过氧化氢降解有机物。水样颗粒被 20-μm 孔径的 Ni 过滤器截留,在室温下干燥,然后通过傅里叶变换显微镜检测和识别 MPs。需要注意的是,污泥样品用过氧化氢处理,并使用碘化钠溶液通过比重分离。然后计算单位体积 MPs 的浓度,并使用水和污泥的流量估算 MPs 的负荷。随后,我们阐明了在污水处理厂中尺寸为 20μm 或更大的 MPs 的命运。当污水厂进水的 MPs 负荷为 100%时,发现有 12%的 MPs 通过污泥处理工艺的侧流回流到污水厂处理工艺。通过这一观察,可以明显看出 MPs 实际上在污水和污泥处理工艺中循环。侧流中的 MPs 主要由污泥浓缩过程的出水组成,大多数 MPs 被认为是纤维状聚对苯二甲酸乙二醇酯(纤维状 MPs,即微纤维 [MFs])。结果表明,MFs 在污水和污泥处理工艺中循环,为了有效提高 MPs 的去除率,在污泥处理工艺中去除 MFs 也相应有效。

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